Synthesis of gold(III) complexes with the 1,2-dithiolate-o-carborane ligand.: Crystal structures of [N(PPh3)2][AuCl2(S2C2B10H10)] and [AuCl(S2C2B10H10)(CH2PPh3)]

被引：20
|
作者：
Crespo, O
Gimeno, MC
Jones, PG
Laguna, A [1 ]
机构：
[1] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, Dept Quim Inorgan, E-50009 Zaragoza, Spain
[2] Tech Univ Carolo Wilhelmina Braunschweig, Inst Anorgan & Analyt Chem, D-38023 Braunschweig, Germany
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 547卷 / 01期
关键词：
gold(III); dithiolate complexes; o-carborane; X-ray structure;
D O I：
10.1016/S0022-328X(97)00268-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of 1,2-dithiol-o-carborane, under basic conditions, with trans-NBu4[AuCl2R2] or [N(PPh3)(2)][AuCl4] results in the formation of the anionic gold(III) derivatives NBu4[(AuR2(S2C2B10H10)] [R = C6F5 (1), C6F3H2 (2)] or [N(PPh3)(2)][AuCl2(S2C2B10H10)] (3). Neutral gold(III) species are synthesized from suitable starting materials such as [AuCl3L] or [AuCl2X(PPh3)], leading to the complexes [AuCl(S2C2B10H10)L] [L = CH2PPh3 (4), CH2PPh2Me (5)] or [AuX(S2C2B10H10)(PPh3)][X = Cl (6), C6F5 (7)]. Complexes 3 and 3 were characterized by X-ray diffraction studies. (C) 1997 Elsevier Science S.A.
引用
收藏
页码：89 / 95
页数：7
相关论文
共 50 条
  • [41] Three monoalkoxy-substituted nido-platinaboranes:: [(PPh3)2PtB10H11-8(OCH3)], [(PPh3)2PtB10H11-8-{OCH(CH3)2}] and [(PPh3)2PtB10H10-9{OCH(CH3)2}]
    Nie, Y
    Hu, CH
    Li, X
    Yong, W
    Dou, JM
    Sun, J
    Jin, RS
    Zheng, PJ
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2001, 57 (08) : 897 - 899
  • [42] Synthesis and characterization of o-carboranylmethyleneamine and o-carboranylmethylenephosphine.: Crystal structure of (H3B)(NMe2CH2CCH) and (C2B10H11)CH2PPh2
    Park, J
    Kim, S
    Ko, J
    Park, K
    Cho, S
    Lee, CH
    Lee, YH
    Kang, SO
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1998, 19 (03) : 363 - 367
  • [43] Synthesis and crystal structure of [(PPh3)(CH3COS)2NiB10H10]•0.4(C5H12)
    Dou, JM
    Hu, CH
    Yao, HJ
    Jin, RS
    Zheng, PJ
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 1999, 18 (05) : 326 - 330
  • [44] Selective Stepwise Substitution in B(3,6) Positions of 16e Half-Sandwich Complex CpCo(S2C2B10H10)
    Ye Hong-De
    Jiang Qi-Bai
    Xie Ming-Shi
    Ding Guan-Yu
    Li Yi-Zhi
    Yan Hong
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2011, 27 (08) : 1601 - 1606
  • [45] Synthesis, Reactivity and Crystal Structures of the Palladium(II) Complexes with the Pyrimidine Containing Ligand: Crystal Structures of [Pd(PPh3)(η1-C4H3N2)(η2-S2CNC4H8)] and [Pd(PPh3)(η1-C4H3N2)(η2-Tp)]
    Wang, Hsiao-Fen
    Yih, Kuang-Hway
    Lee, Gene-Hsiang
    Huang, Shou-Ling
    JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2011, 58 (02) : 174 - 180
  • [46] Reactivity of Half-Sandwich 16e Carborane Complex Me4CpCo[S2C2B10H10] with Phosphorous Compounds
    Y. Huang
    Q. Xiao
    G. R. Xu
    H. D. Ye
    H. N. Peng
    X. L. Zhang
    Russian Journal of Coordination Chemistry, 2023, 49 : 856 - 861
  • [47] REARRANGEMENT OF CLOSO-3,3-(PPH3)2-3-H-1-(R)-3,1,2-IRC2B9H10 TO CLOSO-2,2-(PPH3)2-2-H-8-(R)-2,1,8-IRC2B9H10 - SYNTHESIS AND X-RAY STRUCTURE OF CLOSO-2,2-(PPH3)2-2-H-8-(C6H5)-2,1,8-IRC2B9H10
    DOI, JA
    MIZUSAWA, EA
    KNOBLER, CB
    HAWTHORNE, MF
    INORGANIC CHEMISTRY, 1984, 23 (10) : 1482 - 1484
  • [48] SYNTHESIS AND CRYSTAL-STRUCTURES OF THE GOLD-CARBABORANE COMPLEXES [9-EXO-(AU(PPH3))-9-(MU-H)-10-ENDO-(AU(PPH3))-7,8-ME2-NIDO-7,8-C2B9H8] AND [10-EXO-(AU2(PPH3)2)-10-ENDO-(AU(PPH3))-7,8-ME2-NIDO-7,8-C2B9H8]
    JEFFERY, JC
    JELLISS, PA
    STONE, FGA
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (01): : 25 - 32
  • [49] Rhodium and iridium phosphinothiolato complexes.: Synthesis and crystal structures of mononuclear [M(cod)(S,P-SC2B10H10PPh2)] and dinuclear [M2(CO)2(S,P-μ-SC2B10H10PPh2)] (M = Rh, Ir) and their performance in catalytic carbonylation
    Lee, HS
    Bae, JY
    Kim, DH
    Kim, HS
    Kim, SJ
    Cho, S
    Ko, J
    Kang, SO
    ORGANOMETALLICS, 2002, 21 (01) : 210 - 219
  • [50] Synthesis and crystal structure of three carborane complexes, [M{7,8-(OPPh2)2-7,8-C2B9H10}2] (M = Cu, Zn) and [Ni(thf){7,8-(OPPh2)2-7,8-C2B9H10}2]•thf and two carborane compounds, 1-(OPPh2)-2-(PPh2)-1,2-C2B10H10 and H[7,8-(OPPh2)2-7,8-C2B9H10]-0.25C2H5OH
    Dou, Jianmin
    Zhang, Daopeng
    Li, Dacheng
    Wang, Daqi
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, (01) : 53 - 59
12345