Synthesis of gold(III) complexes with the 1,2-dithiolate-o-carborane ligand.: Crystal structures of [N(PPh3)2][AuCl2(S2C2B10H10)] and [AuCl(S2C2B10H10)(CH2PPh3)]

被引：20
|
作者：
Crespo, O
Gimeno, MC
Jones, PG
Laguna, A [1 ]
机构：
[1] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, Dept Quim Inorgan, E-50009 Zaragoza, Spain
[2] Tech Univ Carolo Wilhelmina Braunschweig, Inst Anorgan & Analyt Chem, D-38023 Braunschweig, Germany
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 547卷 / 01期
关键词：
gold(III); dithiolate complexes; o-carborane; X-ray structure;
D O I：
10.1016/S0022-328X(97)00268-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of 1,2-dithiol-o-carborane, under basic conditions, with trans-NBu4[AuCl2R2] or [N(PPh3)(2)][AuCl4] results in the formation of the anionic gold(III) derivatives NBu4[(AuR2(S2C2B10H10)] [R = C6F5 (1), C6F3H2 (2)] or [N(PPh3)(2)][AuCl2(S2C2B10H10)] (3). Neutral gold(III) species are synthesized from suitable starting materials such as [AuCl3L] or [AuCl2X(PPh3)], leading to the complexes [AuCl(S2C2B10H10)L] [L = CH2PPh3 (4), CH2PPh2Me (5)] or [AuX(S2C2B10H10)(PPh3)][X = Cl (6), C6F5 (7)]. Complexes 3 and 3 were characterized by X-ray diffraction studies. (C) 1997 Elsevier Science S.A.
引用
收藏
页码：89 / 95
页数：7
相关论文
共 50 条
  • [31] Novel group 9 metal complexes containing an S,S'-chelating o-carboranyl ligand system:: Synthesis, crystal structures, and electrochemical properties of dinuclear [{(cod)M}2(S,S'-S2C2B10H10)] (cod=1,5-cyclooctadiene; M = Rh or Ir)] and mononuclear Cp*CoI[S,S-S(S=PMe2)C2B10H10] metal complexes
    Lee, JD
    Kim, BY
    Lee, C
    Lee, YJ
    Ko, J
    Kang, SO
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2004, 25 (07) : 1012 - 1018
  • [32] Reactivity of two MeCp-cobalt complexes containing 1,2-dicarba-closo-dodecaborane-1,2-dichalcogenolate (S2C2B10H10)2– units toward alkynes
    H. D. Ye
    J. R. Hu
    H. N. Peng
    J. L. Xie
    Q. Ye
    Y. H. Li
    Z. S. Xing
    Russian Journal of Coordination Chemistry, 2015, 41 : 585 - 591
  • [33] SYNTHESIS AND CRYSTAL-STRUCTURE OF THE GOLD CARBORANE ANION [11-ENDO-(AU(PPH3))-7,9-ME2-NIDO-7,9-C2B10H10]-
    JEFFERY, JC
    JELLISS, PA
    STONE, FGA
    INORGANIC CHEMISTRY, 1993, 32 (15) : 3382 - 3384
  • [34] METALLAHETEROBORANE CHEMISTRY .7. SYNTHESIS, CRYSTAL-STRUCTURE, AND CHARACTERIZATION OF 2 DINUCLEAR RHODATELLURABORANES, [((PPH3)2RHTEB10H10)2] AND [(PPH3)(CO)RH2TE2B20H20]
    FERGUSON, G
    LOUGH, AJ
    FARIDOON
    MCGRATH, MN
    SPALDING, TR
    KENNEDY, JD
    FONTAINE, XLR
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (06): : 1831 - 1839
  • [35] THE STRUCTURES OF MEP(C2B10H10)2CH2 AND MEAS(C2B10H10)2, COMPOUNDS CONTAINING ORTHO-CARBORANE RING CARBON-ATOMS IN THE HETEROCYCLE
    YANOVSKII, AI
    FURMANOVA, NG
    STRUCHKOV, YT
    SHEMYAKIN, NF
    ZAKHARKIN, LI
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1979, 28 (07): : 1412 - 1417
  • [36] Reactivity of two MeCp-cobalt complexes containing 1,2-dicarba-closo-dodecaborane-1,2-dichalcogenolate (S2C2B10H10)2- units toward alkynes
    Ye, H. D.
    Hu, J. R.
    Peng, H. N.
    Xie, J. L.
    Ye, Q.
    Li, Y. H.
    Xing, Z. S.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2015, 41 (09) : 585 - 591
  • [37] Reactivity of Half-Sandwich 16e Carborane Complex Me4CpCo[S2C2B10H10] with Phosphorous Compounds
    Huang, Y.
    Xiao, Q.
    Xu, G. R.
    Ye, H. D.
    Peng, H. N.
    Zhang, X. L.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2023, 49 (12) : 856 - 861
  • [38] Study of the o-carboranyl fragment as an uncommon substituent.: Crystal structures of [PdClMe(1,2-(PPh2)2-1,2-C2B10H10)]•CH2Cl2 and [PdClMe(1,2-(PiPr2)2-1,2-C2B10H10)] (vol 645, pg 39, 2002)
    Paavola, S
    Teixidor, F
    Viñas, C
    Kivekäs, R
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 654 (1-2) : 237 - 238
  • [39] Silyl group mediated linkage of closo-C2B10-cage to nido-C2B4-carborane:: synthesis of the novel carborane ligand, 1-R-2-[5′-(SiMe2CH2)-2′,3′-(SiMe3)2-2′,3′-C2B4H5]-1,2-C2B10H10 (R = Me, Ph)
    Zhu, YH
    Maguire, JA
    Hosmane, NS
    INORGANIC CHEMISTRY COMMUNICATIONS, 2003, 6 (10) : 1344 - 1346
  • [40] Crystal Structure of {（PPh3）2RuB10H8[（CH3）2CHO]2}
    HU Chun-Hua
    YAO Hai-Jun
    JIN Ruo-Shui
    ENG Pei-Ju(Research Center of Analysis and Measurement
    结构化学, 1997, (04) : 258 - 262
12345