Photoinduced Copper-Catalyzed C-H Arylation at Room Temperature

被引：122
|
作者：
Yang, Fanzhi [1 ]
Koeller, Julian [1 ]
Ackermann, Lutz [1 ,2 ]
机构：
[1] Univ Gottingen, Inst Organ & Biomol Chem, Tammannstr 2, D-37077 Gottingen, Germany
[2] Univ Gottingen, ICASEC, D-37073 Gottingen, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2016年 / 55卷 / 15期
基金：
欧洲研究理事会;
关键词：
alkaloids; C-H activation; copper; photocatalysis; total synthesis; VISIBLE-LIGHT PHOTOREDOX; CARBON-HYDROGEN; CROSS-COUPLINGS; MERGING PHOTOREDOX; NICKEL CATALYSIS; ATOM-TRANSFER; ARYL HALIDES; FUNCTIONALIZATION; PALLADIUM; INDOLES;
D O I：
10.1002/anie.201512027
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Room-temperature azole C-H arylations were accomplished with inexpensive copper(I) compounds by means of photoinduced catalysis. The expedient copper catalysis set the stage for site-selective C-H arylations of non-aromatic oxazolines under mild reaction conditions, and provides step-economical access to the alkaloid natural products balsoxin and texamine.
引用
收藏
页码：4759 / 4762
页数：4
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