Mechanochemical control of solvent content in a 1D coordination polymer

被引：1

作者：

Van Wyk, Lisa M. ^{[1
]}

Loots, Leigh ^{[1
]}

Barbour, Leonard J. ^{[1
]}

机构：

[1] Univ Stellenbosch, Dept Chem & Polymer Sci, ZA-7602 Matieland, South Africa

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2021年 / 74卷 / 1-3期

基金：

新加坡国家研究基金会;

关键词：

Coordination polymer; mechanochemistry; slurry grinding; aging; solvate;

D O I：

10.1080/00958972.2021.1877688

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This study illustrates mechanochemical control over the formation of three coordination polymer solvates. Variation in the onset of grinding, aging after grinding and solvent water content leads to selective preparation of two solvates, which crystallize concomitantly when prepared solvothermally in DMF. A third solvate may be prepared with DMA. Finally, solvent exchange provides means of interconverting between the three solvates.

引用

页码：190 / 199

页数：10

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