An unusual cascade reaction of 4,5-dihydro-4,4-bis(trifluoromethyl)-2-phenyl-6,7-(4-chlorobenzo)[e]-1,3,2-dioxaphosphepin-5-one with chloral

被引：3

作者：

Mironov, Vladimir F. ^{[1
,2
]}

Borisova, Yuliya Yu. ^{[1
]}

Burnaeva, Liliya M. ^{[1
]}

Krivolapov, Dmitry B. ^{[2
]}

Litvinov, Igor A. ^{[2
]}

Zverev, Vladislav V. ^{[2
]}

Musin, Rashid Z. ^{[2
]}

Konovalova, Irina V. ^{[1
]}

机构：

[1] Kazan VI Lenin State Univ, AM Butlerov Chem Inst, Kazan 420008, Russia

[2] Russian Acad Sci, Kazan Sci Ctr, AE Arbuzov Organ & Phys Chem Inst, Kazan 420088, Russia

来源：

MENDELEEV COMMUNICATIONS | 2010年 / 20卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1016/j.mencom.2010.01.017

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of 4,5-dihydro-4,4-bis(trifluoromethyl)-2-phenyl-6,7-(4-chlorobenzo)[e]-1,3,2-dioxaphosphepin-5-one with chloral (1:2) proceeds with evolving hexafluoroacetone and gives spiro{2-oxo-4-trichloromethyl-4,5-dihydro-2-phenyl-6,7-(4-chlorobenzo)[f]-1,3,2-dioxaphosphepine-5,2'-(3-trichloromethyl)oxirane) with a high stereoselectivity. Configuration of the four chiral centres (p(S)(2)C(S)(4)C(S)(5)C(S)5C(S)(3)'/(PRCRCRCR3)-C-2-C-4-C-5') was determined by a single crystal X-ray diffraction.

引用

页码：44 / 46

页数：3

共 42 条

[31] Formation of the P–C and C–C bonds in the Reaction of 2-(5-Methyl-2-phenyl-2H-1,2,3-diazaphosphol-4-yl)-4H-benzo[e]-1,3,2-dioxaphosphorin-4-one with Dimethyl Acetylenedicarboxylate under Mild Conditions
V. F. Mironov
G. A. Ivkova
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L. M. Abdrakhmanova
Russian Journal of General Chemistry, 2018, 88 : 605 - 606
[32] Crystal structure of (3E,5E)-3,5-bis(3-nitrobenzylidene)-1-((4-(trifluoromethyl)phenyl)sulfonyl)piperidin-4-one - dichloromethane (2/1), C53H38Cl2F6N6O14S2
Sun, Yue
Wang, Shu-Xia
Hou, Gui-Ge
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[33] Five-membered 2,3-dioxo heterocycles: LXIII. Cascade recyclization of isopropyl 2-(1-aryl-4,5-dioxo-2-phenyl-4,5-dihydro-1H-pyrrol-3-yl)-2-oxoacetates with cyclic enamines. Crystalline and molecular structure of 1′-benzyl-6′,6′-dimethyl-3-[(Z)-phenyl(phenylamino)methylidene]-6′,7′-dihydro-3H-spiro[furan-2,3′-indole]-2′,4,4′,5(1′H,5′H)-tetraone
P. S. Silaichev
Z. G. Aliev
A. N. Maslivets
Russian Journal of Organic Chemistry, 2009, 45 : 126 - 130
[34] Five-membered 2,3-dioxo heterocycles: LXIII. Cascade recyclization of isopropyl 2-(1-aryl-4,5-dioxo-2-phenyl-4,5-dihydro-1H-pyrrol-3-yl)-2-oxoacetates with cyclic enamines. Crystalline and molecular structure of 1′-benzyl-6′,6′-dimethyl-3-[(Z)-phenyl(phenylamino)methylidene]-6′,7′-dihydro-3H-spiro[furan-2,3′-indole]-2′,4,4′,5(1′H,5′H)-tetraone
Silaichev, P. S.
Aliev, Z. G.
Maslivets, A. N.
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2009, 45 (01) : 126 - 130
[35] Formation of the P-C and C-C bonds in the Reaction of 2-(5-Methyl-2-phenyl-2H-1,2,3-diazaphosphol-4-yl)-4H-benzo[e]-1,3,2-dioxaphosphorin-4-one with Dimethyl Acetylenedicarboxylate under Mild Conditions
Mironov, V. F.
Ivkova, G. A.
Musin, R. Z.
Abdrakhmanova, L. M.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2018, 88 (03) : 605 - 606
[36] PHARMACOLOGICAL PROPERTIES OF 6,7-TETRAMETHYLENE-5-PHENYL-1,2-DIHYDRO-3H-THIENO[2,3-E](1,4)-DIAZEPINE-2-ONE (QM-6008, THIADIPONE), A NEW PSYCHOTROPIC-DRUG
FERNANDEZTOME, MP
FUENTES, JA
MADRONERO, R
DELRIO, J
ARZNEIMITTEL-FORSCHUNG/DRUG RESEARCH, 1975, 25 (06): : 926 - 934
[37] The interaction of 2-(5-methyl-2-phenyl-2h-1,2,3-diazaphosphol-4-yl)-4h-benzo[e]-1,3,2-dioxaphosphinin-4-one with activated carbonyl compounds. Synthesis of bis-heterocyclic systems containing di- and tetracoordinated phosphorus
Mironov, Vladimir F.
Ivkova, Gulnara A.
Abdrakhmanova, Liliya M.
Musin, Rashid Z.
Mironova, Ekaterina V.
Krivolapov, Dmitry B.
Gubaidullin, Aidar T.
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2018, 193 (01) : 53 - 62
[38] Acids and Anions Effects on the Distrubution of Cadmium between Buffered Aqeuous Phases and 4,4′-(1e,1e′)-1,1′-(Ethane-1,2-diylbis(azan-1-yl-1ylidene))bis(5-methyl-2-phenyl-2,3-dihydro-1h-pyrazol-3-ol) solutions
Godwin, J.
Tella, L. S.
Consul, J., I
Ebelegi, A. N.
Ayawei, N.
ORIENTAL JOURNAL OF CHEMISTRY, 2019, 35 (06) : 1702 - 1711
[39] An unusual way of formation of spirophosphoranes during the oxidative addition of hexafluoroacetone to σ5P-σ3P diphosphorus compounds, and in the reaction of 2-chloro-1,2-dimethyl-3-phenyl-2-phenylseleno-1,3,2σ5-diazaphosphetidin-4-one with bis(2-chloroethylamine)hydrochloride/triethylamine (vol 623, pg 1325, 1997)
Neda, I
Pinchuk, VA
Thonnessen, H
Ernst, L
Jones, PG
Schmutzler, R
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1998, 624 (01): : 166 - 166
[40] Five-membered 2,3-dioxo heterocycles: LXXXV. Synthesis of methyl 1-aryl-4,5-dioxo-3-(1-oxo-3-phenylprop-2-en-1-yl)-4,5-dihydro-1H-pyrrole-2-carboxylates and their reaction with 3-amino-5,5-dimethylcyclohex-2-en-1-ones. Molecular and crystalline structure of 4′-hydroxy-1′-(4-methoxyphenyl)-6,6-dimethyl-3′-(1-oxo-3-phenylprop-2-en-1-yl)-1-phenyl-6,7-dihydrospiro[indole-3,2′-pyrrole]-2,4,5′(1H,1′H,5H)-trione
Silaichev, P. S.
Filimonov, V. O.
Slepukhin, P. A.
Maslivets, A. N.
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2012, 48 (04) : 561 - 565

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