Synthesis of alkenylboronates via palladium-catalyzed borylation of alkenyl triflates (or iodides) with pinacolborane

被引:0
|
作者
Murata, M [1 ]
Oyama, T [1 ]
Watanabe, S [1 ]
Masuda, Y [1 ]
机构
[1] Kitami Inst Technol, Dept Mat Sci, Kitami, Hokkaido 0908507, Japan
来源
SYNTHESIS-STUTTGART | 2000年 / 06期
关键词
boron; hydrides; palladium; halides; cross-coupling; triflates;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Various alkenyl iodides and triflates were borylated with pinacolborane in the presence of Et3N and a catalytic amount of PdCl2(dppf) and AsPh3 to afford the corresponding alkenylboronates in good yields.
引用
收藏
页码:778 / 780
页数:3
相关论文
共 50 条
  • [21] A palladium-catalyzed synthesis of cyclic alkenyl boronates from alkenyl chlorides
    Ou, Hongru
    Zhao, Xu
    Luo, Yunfei
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2024, 22 (07) : 1374 - 1377
  • [22] Palladium-catalyzed annulation of internal alkynes by arene-containing vinylic iodides and triflates
    Larock, RC
    Tian, QP
    JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (06): : 2002 - 2009
  • [23] Synthesis of a dicyclobutylideneethane derivative via sequential palladium-catalyzed Miyaura borylation and Suzuki coupling
    Kabalka, GW
    Yao, ML
    TETRAHEDRON LETTERS, 2003, 44 (43) : 7885 - 7887
  • [24] Palladium-Catalyzed Synthesis of Alkynes via a Tandem Decarboxylation/Elimination of (E)-Enol Triflates
    Munteanu, Charissa
    Frantz, Doug E.
    ORGANIC LETTERS, 2016, 18 (16) : 3937 - 3939
  • [25] Palladium-catalyzed cyanation of aryl triflates
    Zhu, Yi-Zhong
    Cai, Chun
    SYNTHETIC COMMUNICATIONS, 2008, 38 (16) : 2753 - 2760
  • [26] Palladium-catalyzed amination of aryl triflates
    Wolfe, JP
    Buchwald, SL
    JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (05): : 1264 - 1267
  • [27] PALLADIUM-CATALYZED OLEFINATION OF VINYL TRIFLATES
    SCOTT, WJ
    PENA, MR
    SWARD, K
    STOESSEL, SJ
    STILLE, JK
    JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (13): : 2302 - 2308
  • [28] Palladium-catalyzed borylation of aryl halides or triflates with dialkoxyborane: A novel and facile synthetic route to arylboronates
    Murata, M
    Oyama, T
    Watanabe, S
    Masuda, Y
    JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (01): : 164 - 168
  • [29] Palladium-catalyzed synthesis of aryl sulfides from aryl triflates
    Zheng, N
    McWilliams, JC
    Fleitz, FJ
    Armstrong, JD
    Volante, RP
    JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (26): : 9606 - 9607
  • [30] SYNTHESIS OF ANTHRAQUINONE DERIVATIVES BY PALLADIUM-CATALYZED COUPLING OF TRIFLATES WITH STANNANES
    TAMAYO, N
    ECHAVARREN, AM
    PAREDES, MC
    FARINA, F
    NOHEDA, P
    TETRAHEDRON LETTERS, 1990, 31 (36) : 5189 - 5192