Microbial Transformation of Prochiral Ketones Using Rhizopus arrhizus

被引：0
|
作者：
Salokhe, Prabha R. [1 ]
Salunkhe, Rajeshri S. [1 ]
机构：
[1] Shivaji Univ, Dept Chem, Kolhapur 416004, Maharashtra, India
来源：
ASIAN JOURNAL OF CHEMISTRY | 2009年 / 21卷 / 06期
关键词：
Biotransformations; Transformation; Prochiral ketones; Rhizopus arrhizus; Bioreduction; Carbinols; ENANTIOMER; REDUCTION;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The various species Of Rhizopus arrhizus have been used tor microbial transformations of p-chloro, p-methyl and p-methoxy propiophenone to synthesize corresponding enantiomerically pure (S) alcohols in 7090 % ee. In a screening of various species of Rhizopus arrhizus for enantioselective reduction of propiophenone derivatives,. Rhizopus arrhizus NCIM-878 showed high activity for reduction of above prochiral ketones and it efficiently hydrolyzes the racemic acetate of p-methoxy propiophenone to corresponding (R) alcohol.
引用
收藏
页码：4333 / 4338
页数：6
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