RETRACTED: The amine-catalysed Suzuki-Miyaura-type coupling of aryl halides and arylboronic acids (Retracted Article)

被引：17

作者：

Xu, Lei ^{[1
]}

Liu, Fu-Yue ^{[1
]}

Zhang, Qi ^{[1
]}

Chang, Wei-Jun ^{[1
]}

Liu, Zhong-Lin ^{[1
]}

Lv, Ying ^{[2
]}

Yu, Hai-Zhu ^{[2
]}

Xu, Jun ^{[1
]}

Dai, Jian-Jun ^{[1
]}

Xu, Hua-Jian ^{[1
]}

机构：

[1] Hefei Univ Technol, Anhui Prov Key Lab Adv Catalyt Mat & React Engn, Inst Ind & Equipment Technol, Sch Food & Biol Engn,Sch Chem & Chem Engn, Hefei, Peoples R China

[2] Anhui Univ, Dept Chem, Anhui Prov Key Lab Chem Inorgan Organ Hybrid Func, Hefei, Peoples R China

来源：

NATURE CATALYSIS | 2021年 / 4卷 / 01期

基金：

中国国家自然科学基金;

关键词：

PINCER COMPLEXES; METAL; PALLADIUM; DERIVATIVES; MECHANISMS; EFFICIENT; RECEPTOR; BIARYLS; ALKYNES;

D O I：

10.1038/s41929-020-00564-z

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Suzuki-Miyaura coupling is a practical and attractive carbon-carbon bond formation reaction due to its high efficiency and wide functional group compatibility, but its industrial applications are limited because it is typically catalysed by expensive palladium-containing transition-metal complexes. Here we show a robust and chemoselective organocatalytic Suzuki-Miyaura-type coupling of aryl halides with arylboronic acids catalysed by amines. The utility and scope of this reaction were demonstrated by the synthesis of several commercially relevant small molecules and a selection of derivatives of pharmaceutical drugs.

引用

页码：71 / 78

页数：8

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