Novel coordination of dicyanamide, [N(CN)2]-:: preferential binding of the amide nitrogen

被引：57

作者：

Marshall, SR

Incarvito, CD

Shum, WW

Rheingold, AL

Miller, JS

机构：

[1] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA

[2] Univ Delaware, Dept Chem, Newark, DE 19716 USA

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 24期

关键词：

D O I：

10.1039/b208872j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

C-II[N(CN)(2)](2)(H(2)BiIm)(2), 1, and {Co-II[N(CN)(2)](H2BiIM)(2)}Cl, 2 (H(2)BiIm = 2,2'-biimidazole) have been structurally, spectroscopically, and magnetically characterized with both containing dicyanamides bound in unprecedented manners; namely, solely via the amide nitrogen for 1, and via an imide N forming 1-D helical chains for 2.

引用

页码：3006 / 3007

页数：2

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