Novel coordination of dicyanamide, [N(CN)2]-:: preferential binding of the amide nitrogen

被引：57
|
作者：
Marshall, SR
Incarvito, CD
Shum, WW
Rheingold, AL
Miller, JS
机构：
[1] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA
[2] Univ Delaware, Dept Chem, Newark, DE 19716 USA
来源：
CHEMICAL COMMUNICATIONS | 2002年 / 24期
关键词：
D O I：
10.1039/b208872j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
C-II[N(CN)(2)](2)(H(2)BiIm)(2), 1, and {Co-II[N(CN)(2)](H2BiIM)(2)}Cl, 2 (H(2)BiIm = 2,2'-biimidazole) have been structurally, spectroscopically, and magnetically characterized with both containing dicyanamides bound in unprecedented manners; namely, solely via the amide nitrogen for 1, and via an imide N forming 1-D helical chains for 2.
引用
收藏
页码：3006 / 3007
页数：2
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