Novel coordination of dicyanamide, [N(CN)2]-:: preferential binding of the amide nitrogen

被引：57
|
作者：
Marshall, SR
Incarvito, CD
Shum, WW
Rheingold, AL
Miller, JS
机构：
[1] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA
[2] Univ Delaware, Dept Chem, Newark, DE 19716 USA
来源：
CHEMICAL COMMUNICATIONS | 2002年 / 24期
关键词：
D O I：
10.1039/b208872j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
C-II[N(CN)(2)](2)(H(2)BiIm)(2), 1, and {Co-II[N(CN)(2)](H2BiIM)(2)}Cl, 2 (H(2)BiIm = 2,2'-biimidazole) have been structurally, spectroscopically, and magnetically characterized with both containing dicyanamides bound in unprecedented manners; namely, solely via the amide nitrogen for 1, and via an imide N forming 1-D helical chains for 2.
引用
收藏
页码：3006 / 3007
页数：2
相关论文
共 50 条
  • [1] Two new dicyanamide coordination polymers with alternating parallel chains:: {Mn(dmpz)[N(CN)2]2)2 and {Cu(dmpz)[N(CN)2]2)2
    Luo, J
    Zhou, XG
    Hou, XF
    Wu, HX
    Weng, LH
    Li, YR
    CHINESE JOURNAL OF CHEMISTRY, 2005, 23 (03) : 310 - 314
  • [2] Magnetic Materials Containing the Dicyanamide Anion, {N(Cn)2}-
    Kurmoo, Mohamedally
    Kepert, Cameron J.
    Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 334 : 693 - 702
  • [3] Magnetic materials containing the dicyanamide anion, {N(Cn)2}-
    Kurmoo, M
    Kepert, CJ
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1999, 334 : 693 - 702
  • [4] Buckled-layered structure of zinc dicyanamide, ZnII[N(CN)2]2
    Manson, JL
    Lee, DW
    Rheingold, AL
    Miller, JS
    INORGANIC CHEMISTRY, 1998, 37 (23) : 5966 - 5967
  • [5] Synthesis and Characterization of the New Dicyanamide LiCs2[N(CN)(2)](3)
    Mann, Markus
    Reckeweg, Olaf
    Dronskowski, Richard
    INORGANICS, 2018, 6 (04):
  • [6] Syntheses and Characterization of Two Dicyanamide Compounds Containing Monovalent Cations: Hg-2[N(CN)(2)](2) and Tl[N(CN)(2)]
    Mann, Markus
    Reckeweg, Olaf
    Noethling, Nils
    Goddard, Richard
    Dronskowski, Richard
    INORGANICS, 2018, 6 (04):
  • [7] Experimental and Theoretical Studies of the Reactivity and Thermochemistry of Dicyanamide: N(CN)2-
    Nichols, Charles M.
    Wang, Zhe-Chen
    Yang, Zhibo
    Lineberger, W. Carl
    Bierbaum, Veronica M.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2016, 120 (07): : 992 - 999
  • [8] Pb(dca)2 (dca = dicyanamide):: a novel 3D compound with unusual coordination modes of dicyanamide
    Shi, YJ
    Chen, XT
    Li, YZ
    Xue, ZL
    You, XZ
    NEW JOURNAL OF CHEMISTRY, 2002, 26 (12) : 1711 - 1713
  • [9] Hard magnets based on transition metal complexes with the dicyanamide anion, {N(CN)2}-
    Kurmoo, M
    Kepert, CJ
    NEW JOURNAL OF CHEMISTRY, 1998, 22 (12) : 1515 - 1524
  • [10] Microsolvation of the dicyanamide anion: [N(CN)2-](H2O)n (n=0-12)
    Wang, Xue-Bin
    Jagoda-Cwiklik, Barbara
    Woo, Hin-Koon
    Yang, Jie
    Wang, Guan-Jun
    Zhou, Mingfei
    Jungwirth, Pavel
    Wang, Lai-Sheng
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 234
12345