Time-resolved surface X-ray scattering study of surface ordering of electrodeposited layers

被引：7
|
作者：
Finnefrock, AC
Buller, LJ
Ringland, KL
Brock, JD
Abruna, HD
机构：
[1] CORNELL UNIV,SCH APPL & ENGN PHYS,ITHACA,NY 14853
[2] CORNELL UNIV,DEPT PHYS,ITHACA,NY 14853
[3] CORNELL UNIV,DEPT CHEM,ITHACA,NY 14853
[4] CORNELL UNIV,CTR MAT SCI,ITHACA,NY 14853
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1997年 / 119卷 / 48期
关键词：
D O I：
10.1021/ja971457k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In order to clarify the time evolution of underpotential deposition (UPD), time-resolved surface X-ray scattering combined with chronoamperometric measurements were carried out on Cu UPD on Pt(111) in the presence of Cl-. Measurements were performed at the X20A beamline. A thin polypropylene film covered the sample and contained the solution in a thin layer configuration. The results show that the electrochemical deposition/stripping processes are far more rapid than the time required to form an ordered CuCl overlayer.
引用
收藏
页码：11703 / 11704
页数：2
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