Crystal structure of a supramolecular cluster adduct with cucurbituril, (H3O)4[W3S7Cl6]2(C36N24O12H36)•8H2O

被引：0
|
作者：
Geras'ko, OA
Virovets, AV
Dybtsev, DN
Klegg, V
Fedin, VP
机构：
[1] Russian Acad Sci, Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
[2] Newcastle Univ, Dept Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2000年 / 26卷 / 07期
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D O I：
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中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structure of (H3O)(4)[W3S7Cl6](2)(C36N24O12H36). 8H(2)O was determined. It crystallizes in the monoclinic system with a = 38.687(2), b = 18.127(1), c = 12.5760(7) Angstrom, beta = 94.185(1)degrees, space group C2/c, Z = 4, Pealed = 2.412 g/cm(3). The crystal lattice consists of alternating layers of cucurbituril molecules arranged in a parquet fashion and dimers of cluster anions. A comparison was made with the previously obtained supramolecular molybdenum and the tungsten aqua complexes with cucurbituril.
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页码：478 / 481
页数：4
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