Copper(I) complex of 2,2′-biquinoline assembled by non-covalent interactions

被引：1

作者：

Li, Tao ^{[1
]}

Chen, Jie-bo ^{[1
]}

Wu, Lei-Jiang ^{[1
]}

Lin, Min ^{[1
]}

Huang, Biao ^{[2
]}

机构：

[1] Fujian Agr & Forestry Univ, Sch Life Sci, Fuzhou 350002, Fujian, Peoples R China

[2] Fujian Agr & Forestry Univ, Mat Engn Coll, Fuzhou 350002, Fujian, Peoples R China

来源：

JOURNAL OF CHEMICAL RESEARCH | 2009年 / 09期

基金：

美国国家科学基金会;

关键词：

crystal structure; hydrogen bond; pi-pi interaction; copper(I); PI-PI STACKING; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURE; CHEMISTRY;

D O I：

10.3184/030823409X12498344384876

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new 3-D supramolecular Cu(I) complex, [Cu(biq)Cl] (biq = 2,2'-biquinoline), (1), has been synthesised and characterised. Single-crystal analysis shows that 1 contains 2-D layers linked by C-H center dot center dot center dot Cl interactions and the copper centres adopts a distorted trigonal planar geometry. Moreover there are pi-pi interactions between aromatic rings of the ligands, which connect the layers to form a 3-D supramolecular network.

引用

页码：549 / 551

页数：3

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