Copper(I) complex of 2,2′-biquinoline assembled by non-covalent interactions

被引：1
|
作者：
Li, Tao [1 ]
Chen, Jie-bo [1 ]
Wu, Lei-Jiang [1 ]
Lin, Min [1 ]
Huang, Biao [2 ]
机构：
[1] Fujian Agr & Forestry Univ, Sch Life Sci, Fuzhou 350002, Fujian, Peoples R China
[2] Fujian Agr & Forestry Univ, Mat Engn Coll, Fuzhou 350002, Fujian, Peoples R China
来源：
JOURNAL OF CHEMICAL RESEARCH | 2009年 / 09期
基金：
美国国家科学基金会;
关键词：
crystal structure; hydrogen bond; pi-pi interaction; copper(I); PI-PI STACKING; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURE; CHEMISTRY;
D O I：
10.3184/030823409X12498344384876
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new 3-D supramolecular Cu(I) complex, [Cu(biq)Cl] (biq = 2,2'-biquinoline), (1), has been synthesised and characterised. Single-crystal analysis shows that 1 contains 2-D layers linked by C-H center dot center dot center dot Cl interactions and the copper centres adopts a distorted trigonal planar geometry. Moreover there are pi-pi interactions between aromatic rings of the ligands, which connect the layers to form a 3-D supramolecular network.
引用
收藏
页码：549 / 551
页数：3
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