Copper(I) complex of 2,2′-biquinoline assembled by non-covalent interactions

被引：1
|
作者：
Li, Tao [1 ]
Chen, Jie-bo [1 ]
Wu, Lei-Jiang [1 ]
Lin, Min [1 ]
Huang, Biao [2 ]
机构：
[1] Fujian Agr & Forestry Univ, Sch Life Sci, Fuzhou 350002, Fujian, Peoples R China
[2] Fujian Agr & Forestry Univ, Mat Engn Coll, Fuzhou 350002, Fujian, Peoples R China
来源：
JOURNAL OF CHEMICAL RESEARCH | 2009年 / 09期
基金：
美国国家科学基金会;
关键词：
crystal structure; hydrogen bond; pi-pi interaction; copper(I); PI-PI STACKING; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURE; CHEMISTRY;
D O I：
10.3184/030823409X12498344384876
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new 3-D supramolecular Cu(I) complex, [Cu(biq)Cl] (biq = 2,2'-biquinoline), (1), has been synthesised and characterised. Single-crystal analysis shows that 1 contains 2-D layers linked by C-H center dot center dot center dot Cl interactions and the copper centres adopts a distorted trigonal planar geometry. Moreover there are pi-pi interactions between aromatic rings of the ligands, which connect the layers to form a 3-D supramolecular network.
引用
收藏
页码：549 / 551
页数：3
相关论文
共 50 条
  • [1] COPPER (I)-2,2'-BIQUINOLINE COMPLEX IN AQUEOUS DIMETHYLFORMAMIDE
    PFLAUM, RT
    POPOV, AI
    GOODSPEED, NC
    ANALYTICAL CHEMISTRY, 1955, 27 (02) : 253 - 255
  • [2] Effects of non-covalent interactions on the electronic and electrochemical properties of Cu(i) biquinoline complexes
    Martinez, Natalia P.
    Isaacs, Mauricio
    Oliver, Allen G.
    Ferraudi, G.
    Lappin, A. Graham
    Guerrero, Juan
    DALTON TRANSACTIONS, 2018, 47 (37) : 13171 - 13179
  • [3] (2,2′-Biquinoline-κ2 N,N′) bis(triphenylphosphine-κP)-copper(I) nitrate 2,2′-biquinoline hemisolvate hemihydrate
    Navarro, Maribel
    Corona, Oscar
    Gonzalez, Teresa
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : M1153 - M1155
  • [4] Non-covalent interactions in 2-phenylethylammonium perhalometallates
    Rademeyer, Melanie
    Tsouris, Christos P.
    Billing, David
    Lemmerer, Andreas
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2006, 62 : S178 - S178
  • [5] Supramolecular and theoretical investigation of copper(II) complexes containing 2,2'-39;-bipyridine and substituted chalcone ligands: Estimation of non-covalent interactions
    Gaur, Ruchi
    Mishra, Lallan
    JOURNAL OF MOLECULAR STRUCTURE, 2023, 1273
  • [6] Interconversion of copper(II) to copper(I):: synthesis, characterization of copper(II) and copper(I) 2,2′-biquinoline complexes and their microbiological activity
    Ali, BF
    Sou'od, KA
    Al-Ja'ar, N
    Nassar, A
    Zaghal, MH
    Judeh, Z
    Al-Far, R
    Al-Refai, M
    Ibrahim, M
    Mansi, K
    Al-Obaidi, KH
    JOURNAL OF COORDINATION CHEMISTRY, 2006, 59 (02) : 229 - 241
  • [7] Non-covalent interactions
    Schneider, HJ
    JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 1997, 10 (05) : 253 - 253
  • [8] Non-covalent Interactions
    Sochneider, H.-J.
    Journal of Physical Organic Chemistry, 10 (05):
  • [9] Intramolecular non-covalent interactions as a strategy towards controlled photoluminescence in copper(I) complexes
    Filonenko, G. A.
    Fayzullin, R. R.
    Khusnutdinova, J. R.
    JOURNAL OF MATERIALS CHEMISTRY C, 2017, 5 (07) : 1638 - 1645
  • [10] Spectroscopic and electrochemical properties of heteroleptic cationic copper complexes bis-(diphenylphosphino) alkane-(2,2′-biquinoline) copper(I). Crystal structure of bis(diphenylphosphino) ethane-(2,2′-biquinoline) copper(I) perchlorate
    Guerrero, Juan
    Cortez, Luis
    Lemus, Luis
    Farias, Liliana
    Costamagna, Juan
    Pettinari, Claudio
    Rossi, Miriam
    Caruso, Francesco
    INORGANICA CHIMICA ACTA, 2010, 363 (14) : 3809 - 3816
12345