Multitopic Ligand Design: A Concept for Single-Source Precursors

被引：41

作者：

Gschwind, Fabienne ^{[1
]}

Sereda, Olha ^{[2
]}

Fromm, Katharina M. ^{[1
]}

机构：

[1] Univ Fribourg, Dept Chem, CH-1700 Fribourg, Switzerland

[2] CSEM Ctr Suisse Elect & Microtech SA, CH-2002 Neuchatel, Switzerland

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 22期

基金：

瑞士国家科学基金会;

关键词：

CHEMICAL-VAPOR-DEPOSITION; BETA-DIKETONATE COMPLEXES; METAL-ORGANIC FRAMEWORKS; BOND VALENCE SUMS; CRYSTAL-STRUCTURE; ETHANEDIYL BIS(ISONICOTINATE); STRUCTURAL-CHARACTERIZATION; THIN-FILMS; HETEROMETALLIC ALKOXIDES; COORDINATION CHEMISTRY;

D O I：

10.1021/ic9009064

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The multitopic ligand O,O'-bisnicotinic acid tetraethylene glycol, L, was designed for the coordination of two distinct types of metal ions. In this work, we describe how the O-donor part of L is used to coordinate to alkaline earth metal ions and that the N-donor atoms of L bind to group 11 elements. This makes L a suitable ligand for the combination of both metal ion types within the same compound. This concept will be exemplified by highlighting the pure Ca2+ complexes, a Cu+-coordination polymer network, as well as the mixed-metal compound, which can be used as a single-source precursor for mixed-metal oxide materials.

引用

页码：10535 / 10547

页数：13

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