Multitopic Ligand Design: A Concept for Single-Source Precursors

被引：41
|
作者：
Gschwind, Fabienne [1 ]
Sereda, Olha [2 ]
Fromm, Katharina M. [1 ]
机构：
[1] Univ Fribourg, Dept Chem, CH-1700 Fribourg, Switzerland
[2] CSEM Ctr Suisse Elect & Microtech SA, CH-2002 Neuchatel, Switzerland
来源：
INORGANIC CHEMISTRY | 2009年 / 48卷 / 22期
基金：
瑞士国家科学基金会;
关键词：
CHEMICAL-VAPOR-DEPOSITION; BETA-DIKETONATE COMPLEXES; METAL-ORGANIC FRAMEWORKS; BOND VALENCE SUMS; CRYSTAL-STRUCTURE; ETHANEDIYL BIS(ISONICOTINATE); STRUCTURAL-CHARACTERIZATION; THIN-FILMS; HETEROMETALLIC ALKOXIDES; COORDINATION CHEMISTRY;
D O I：
10.1021/ic9009064
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The multitopic ligand O,O'-bisnicotinic acid tetraethylene glycol, L, was designed for the coordination of two distinct types of metal ions. In this work, we describe how the O-donor part of L is used to coordinate to alkaline earth metal ions and that the N-donor atoms of L bind to group 11 elements. This makes L a suitable ligand for the combination of both metal ion types within the same compound. This concept will be exemplified by highlighting the pure Ca2+ complexes, a Cu+-coordination polymer network, as well as the mixed-metal compound, which can be used as a single-source precursor for mixed-metal oxide materials.
引用
收藏
页码：10535 / 10547
页数：13
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