Sensing of polymeric sensor-based rhodamine B derivative for metal cations in complete aqueous solution

被引：10

作者：

Geng, Tong-Mou ^{[1
]}

Wang, Xie ^{[1
]}

Zhu, Feng ^{[1
]}

Jiang, Hui ^{[1
]}

Wang, Yu ^{[2
]}

机构：

[1] Anqing Normal Univ, Collaborat Innovat Ctr Petrochem New Mat, Sch Chem & Chem Engn, Anhui Key Lab Funct Coordinat Cpds, Anqing 246011, Peoples R China

[2] Anqing Normal Univ, Sch Resource & Environm Sci, Anqing 246011, Peoples R China

来源：

BULLETIN OF MATERIALS SCIENCE | 2017年 / 40卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Fluorescent sensor; water-soluble polymer; rhodamine B; diethylenetriamine; acrylamide; ON FLUORESCENT CHEMOSENSOR; ACRYLIC-ACID; OFF-ON; PRECIPITATION POLYMERIZATION; HG2+ IONS; FE3+; BEHAVIOR; DESIGN; PROBE; FRET;

D O I：

10.1007/s12034-016-1325-5

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The water-soluble polymeric chemosensor poly(AM-GRBD) has been synthesized by precipitation copolymerization with the functional monomer, GRBD, which was made of N''-(rhodamine B-yl) diethylenetriamine and glycidyl methacrylate (GMA) and a hydrophilic co-monomer acrylamide (AM). The chemical sensor behaved as a fluorescent and chromogenic sensor towards various heavy metal cations and transition metal cations; particularly, Cr3+, Fe3+ and Hg2+ ions in completely aqueous media. The fluorescence of poly(AM-GRBD) was enhanced by Cr3+, Fe3+ and Hg2+ metal ions. Moreover, during titration of Cr3+, Hg2+ or Fe3+ to the aqueous solution of poly(AM-GRBD), the visual colour changed from colourless to pink or brown yellow under visible light.

引用

页码：187 / 193

页数：7

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