Thermo and pH sensitive fluorescent polymer sensor for metal cations in aqueous solution

被引：30
|
作者：
Liu, Yunhai [1 ,2 ]
Meng, Lingzhi [1 ]
Lu, Xiaoju [1 ]
Zhang, Lifen [1 ]
He, Yongbing [1 ]
机构：
[1] Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
[2] E China Inst Technol, Dept Appl Chem, Fuzhou 344000, Peoples R China
来源：
POLYMERS FOR ADVANCED TECHNOLOGIES | 2008年 / 19卷 / 02期
关键词：
N-acryl-N '-(quinolin-8-yl)thiourea; poly(N-isopropylacrylamide); fluorescence; thermo-sensitive; Co2+ ion;
D O I：
10.1002/pat.986
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A new monomeric fluorophore N-acryl-N'-(quinolin-8-yl)thiourea (AQT) was synthesized. Free radical copolymerization was carried out in order to prepare a water-soluble fluorescent copolymer, based on N-isopropylacrylamide. The fluorescent characteristic of the aqueous solutions of copolymers was investigated both in varied pH and in the presence of metal cations. The polymer-contained AQT was found to be a selective chemosensor for Ni, Pb, Co ions especially for Co ion. The obtained copolymers show thermo-sensitive lower critical solution temperature (LCST) ranging from 32.5 to 37.5 degrees C with varied ratios of AQT, N, N-dimethylacrylamide and N-isopropylamide. Copyright (C) 2007 John Wiley & Sons, Ltd.
引用
收藏
页码：137 / 143
页数：7
相关论文
共 50 条
  • [1] pH- and Thermo-responsive Polymer Assemblies in Aqueous Solution
    Siband, Elodie
    Tran, Yvette
    Hourdet, Dominique
    [J]. TRENDS IN COLLOID AND INTERFACE SCIENCE XXIII, 2010, 137 : 19 - 22
  • [2] A New Fluorescent Sensor for Transition Metal Ions in Aqueous Solution
    Li Jian JIANG
    Zhi Lin WANG
    Xiao Qing JIANG
    Qin Hui LUO(Coordination Chemistry Institute Nanjing University Nanjing 210093)
    [J]. Chinese Chemical Letters, 2000, (06) : 551 - 554
  • [3] A new fluorescent sensor for transition metal ions in aqueous solution
    Jiang, LJ
    Wang, ZL
    Jiang, XQ
    Luo, QH
    [J]. CHINESE CHEMICAL LETTERS, 2000, 11 (06) : 551 - 554
  • [4] An efficient and sensitive fluorescent pH sensor based on amino functional metal-organic frameworks in aqueous environment
    Xu, Xiao-Yu
    Yan, Bing
    [J]. DALTON TRANSACTIONS, 2016, 45 (16) : 7078 - 7084
  • [5] A fluorescent sensor for selective, sensitive, and recyclable detection of mercury(II) in aqueous solution based on a zinc(II) coordination polymer
    Zhang, Shu-Ran
    Wang, Wei
    Xu, Guang-Juan
    Yao, Chan
    Xu, Yan-Hong
    Su, Zhong-Min
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2018, 89 : 73 - 77
  • [6] Sensitive detection of picric acid in an aqueous solution using fluorescent nonconjugated polymer dots as fluorescent probes
    Liu, Jinshui
    Fu, Ting
    Liu, Chenfu
    Wu, Fangfei
    Wang, Huaxin
    [J]. NANOTECHNOLOGY, 2021, 32 (35)
  • [7] Synthesis of carboxymethyl chitin in aqueous solution and its thermo- and pH-sensitive behaviors
    Liu, Hui
    Yang, Qizhi
    Zhang, Lina
    Zhuo, Renxi
    Jiang, Xulin
    [J]. CARBOHYDRATE POLYMERS, 2016, 137 : 600 - 607
  • [8] Preparation and application of a highly sensitive conjugated polymer-copper (II) composite fluorescent sensor for detecting hydrazine in aqueous solution
    Hu, Zhiru
    Yang, Ting
    Liu, Jilin
    Zhang, Zhiquan
    Feng, Guodong
    [J]. TALANTA, 2020, 207
  • [9] Interaction of quinolones with metal cations in aqueous solution
    Kawai, Y
    Matsubayashi, K
    Hakusui, H
    [J]. CHEMICAL & PHARMACEUTICAL BULLETIN, 1996, 44 (08) : 1425 - 1430
  • [10] A thermal and pH stable fluorescent coordination polymer for sensing nitro explosives or metal ions with high selectivity and sensitivity in aqueous solution
    Zhang, Lei
    Hu, Jinsong
    Li, Jiaxin
    Zhang, Jing
    [J]. JOURNAL OF LUMINESCENCE, 2021, 234
12345