Sensing of polymeric sensor-based rhodamine B derivative for metal cations in complete aqueous solution

被引：10
|
作者：
Geng, Tong-Mou [1 ]
Wang, Xie [1 ]
Zhu, Feng [1 ]
Jiang, Hui [1 ]
Wang, Yu [2 ]
机构：
[1] Anqing Normal Univ, Collaborat Innovat Ctr Petrochem New Mat, Sch Chem & Chem Engn, Anhui Key Lab Funct Coordinat Cpds, Anqing 246011, Peoples R China
[2] Anqing Normal Univ, Sch Resource & Environm Sci, Anqing 246011, Peoples R China
来源：
BULLETIN OF MATERIALS SCIENCE | 2017年 / 40卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Fluorescent sensor; water-soluble polymer; rhodamine B; diethylenetriamine; acrylamide; ON FLUORESCENT CHEMOSENSOR; ACRYLIC-ACID; OFF-ON; PRECIPITATION POLYMERIZATION; HG2+ IONS; FE3+; BEHAVIOR; DESIGN; PROBE; FRET;
D O I：
10.1007/s12034-016-1325-5
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The water-soluble polymeric chemosensor poly(AM-GRBD) has been synthesized by precipitation copolymerization with the functional monomer, GRBD, which was made of N''-(rhodamine B-yl) diethylenetriamine and glycidyl methacrylate (GMA) and a hydrophilic co-monomer acrylamide (AM). The chemical sensor behaved as a fluorescent and chromogenic sensor towards various heavy metal cations and transition metal cations; particularly, Cr3+, Fe3+ and Hg2+ ions in completely aqueous media. The fluorescence of poly(AM-GRBD) was enhanced by Cr3+, Fe3+ and Hg2+ metal ions. Moreover, during titration of Cr3+, Hg2+ or Fe3+ to the aqueous solution of poly(AM-GRBD), the visual colour changed from colourless to pink or brown yellow under visible light.
引用
收藏
页码：187 / 193
页数：7
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