Characterization of Monomer Emulsions in Terms of Droplet Size and Stability: Effect of Emulsifier Concentration

被引:3
|
作者
Celis, Maria-Teresa [1 ,2 ]
Gil, Andres [1 ]
Forgiarini, Ana [1 ,2 ]
Garcia-Rubio, Luis H. [3 ]
机构
[1] Univ Los Andes, Lab Polimeros & Coloides, Dept Chem Engn, Merida 5101, Venezuela
[2] Univ Los Andes, Lab FIRP, Dept Chem Engn, Merida 5101, Venezuela
[3] Univ S Florida, Coll Marine Sci, St Petersburg, FL 33701 USA
关键词
Droplet size; emulsion; emulsion polymerization; multiwavelength spectroscopy; stability; OIL-WATER SYSTEMS; AFFINITY INVERSION; FORMULATION; SPECTROSCOPY; STYRENE; PHASE;
D O I
10.1080/01932690902735595
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In emulsification processes, the estimation of the droplet size distribution is important data not only because it is linked with the manufacturing process, but also because it is an important parameter affecting the emulsion stability. The aim of this research is to use the ultraviolet-visible transmission spectrum as a tool for emulsion characterization (droplet size and stability) to be a function of monomer concentration, and to verify of emulsion stability using the volume of separated phase's technique. Both techniques are applied to monomer emulsions as a function of emulsifier concentration. Results show correlations between droplet size measurements and stability of emulsions using the spectroscopy technique; results were also found to be in agreement using the cleared volume method.
引用
收藏
页码:1384 / 1389
页数:6
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