Characterization of Monomer Emulsions in Terms of Droplet Size and Stability: Effect of Emulsifier Concentration

被引:3
|
作者
Celis, Maria-Teresa [1 ,2 ]
Gil, Andres [1 ]
Forgiarini, Ana [1 ,2 ]
Garcia-Rubio, Luis H. [3 ]
机构
[1] Univ Los Andes, Lab Polimeros & Coloides, Dept Chem Engn, Merida 5101, Venezuela
[2] Univ Los Andes, Lab FIRP, Dept Chem Engn, Merida 5101, Venezuela
[3] Univ S Florida, Coll Marine Sci, St Petersburg, FL 33701 USA
关键词
Droplet size; emulsion; emulsion polymerization; multiwavelength spectroscopy; stability; OIL-WATER SYSTEMS; AFFINITY INVERSION; FORMULATION; SPECTROSCOPY; STYRENE; PHASE;
D O I
10.1080/01932690902735595
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In emulsification processes, the estimation of the droplet size distribution is important data not only because it is linked with the manufacturing process, but also because it is an important parameter affecting the emulsion stability. The aim of this research is to use the ultraviolet-visible transmission spectrum as a tool for emulsion characterization (droplet size and stability) to be a function of monomer concentration, and to verify of emulsion stability using the volume of separated phase's technique. Both techniques are applied to monomer emulsions as a function of emulsifier concentration. Results show correlations between droplet size measurements and stability of emulsions using the spectroscopy technique; results were also found to be in agreement using the cleared volume method.
引用
收藏
页码:1384 / 1389
页数:6
相关论文
共 50 条
  • [21] Oxidation of linoleic acid in emulsions: Effect of substrate, emulsifier, and sugar concentration
    Ponginebbi, L.
    Nawar, W.W.
    Chinachoti, P.
    JAOCS, Journal of the American Oil Chemists' Society, 1999, 76 (01): : 131 - 138
  • [22] The effect of emulsifier concentration on the lubricating properties of oil-in-water emulsions
    A. Cambiella
    J. M. Benito
    C. Pazos
    J. Coca
    M. Ratoi
    H. A. Spikes
    Tribology Letters, 2006, 22
  • [23] Oxidation of linoleic acid in emulsions: Effect of substrate, emulsifier, and sugar concentration
    Ponginebbi, L
    Nawar, WW
    Chinachoti, P
    JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1999, 76 (01) : 131 - 138
  • [24] Droplet-size distribution and stability of lipid injectable emulsions
    Gallegos, Crispulo
    Partal, Pedro
    Franco, Jose M.
    AMERICAN JOURNAL OF HEALTH-SYSTEM PHARMACY, 2009, 66 (02) : 162 - 166
  • [25] The effect of emulsifier concentration on the lubricating properties of oil-in-water emulsions
    Cambiella, A.
    Benito, J. M.
    Pazos, C.
    Coca, J.
    Ratoi, M.
    Spikes, H. A.
    TRIBOLOGY LETTERS, 2006, 22 (01) : 53 - 65
  • [26] The effect of preparation technique on droplet size in silicone emulsions
    Gallardo, V
    Hernández, A
    Parera, A
    Ruiz, MA
    JOURNAL OF COSMETIC SCIENCE, 1999, 50 (01): : 9 - 14
  • [27] Influence of droplet size and concentration on the color of oil-in-water emulsions
    Chantrapornchai, W
    Clydesdale, F
    McClements, DJ
    JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1998, 46 (08) : 2914 - 2920
  • [28] INFLUENCE OF CONCENTRATION AND DROPLET SIZE OF EMULSIONS ON THEIR EFFICIENCY IN COLD-ROLLING
    PIMENOV, AF
    SHAKHOV, VL
    VASILEV, AV
    TRAINO, AI
    BUKHANOV, AN
    SAFIN, GG
    STEEL IN THE USSR, 1987, 17 (05): : 228 - 229
  • [29] Characterization of the droplet size of emulsions and its influence on the rheological behaviour
    Teipel, U
    Aksel, N
    ANTEC '96: PLASTICS - RACING INTO THE FUTURE, VOLS I-III: VOL I: PROCESSING; VOL II: MATERIALS; VOL III: SPACIAL AREAS, 1996, 42 : 3665 - 3667
  • [30] Spray drying of emulsions: Influence of the emulsifier system on changes in oil droplet size during the drying step
    Taboada, Martha L.
    Heiden-Hecht, Theresia
    Brueckner-Guehmann, Monika
    Karbstein, Heike P.
    Drusch, Stephan
    Gaukel, Volker
    JOURNAL OF FOOD PROCESSING AND PRESERVATION, 2021, 45 (09)