Nitric Oxide Chemisorption in a Postsynthetically Modified Metal-Organic Framework

被引：103
|
作者：
Ingleson, Michael J. [1 ]
Heck, Romain [1 ]
Gould, Jamie A. [1 ]
Rosseinsky, Matthew J. [1 ]
机构：
[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England
来源：
INORGANIC CHEMISTRY | 2009年 / 48卷 / 21期
基金：
英国工程与自然科学研究理事会;
关键词：
COORDINATION; ADSORPTION; STORAGE; NO; FUNCTIONALIZATION; CATALYSIS; BINDING;
D O I：
10.1021/ic9015977
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Postsynthetic metal-organic framework (MOF) derivatization introduces accessible secondary amine functionalities that react with nitric oxide (NO) to form N-diazenium diolates. This is in contrast to the parent MOF that binds NO essentially irreversibly at open metal coordination sites.
引用
收藏
页码：9986 / 9988
页数：3
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