Asymmetric aminohydroxylation of heteroaromatic acrylates

被引：0

作者：

Raatz, D ^{[1
]}

Innertsberger, C ^{[1
]}

Reiser, O ^{[1
]}

机构：

[1] Univ Regensburg, Inst Organ Chem, D-93040 Regensburg, Germany

来源：

SYNLETT | 1999年 / 12期

关键词：

aminohydroxylations; amino acids; asymmetric catalysis; taxol (TM) (paclitaxel); pyridines;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-, S- and O-heteroaromatic acrylates were amino-hydroxylated with generally high regio- and enantioselectivity. While pyridylacrylates are not amenable towards this process, the corresponding N-oxides proved to be a useful substitute, allowing the access to biologically important pyridine substituted taxol(TM) side chain analogs.

引用

页码：1907 / 1910

页数：4

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