Improved Pt-utilization efficiency of low Pt-loading PEM fuel cell electrodes using direct membrane deposition

Direct membrane deposition was used to produce record platinum catalyst utilization efficiency polymer electrolyte membrane fuel cells. The novel membrane fabrication technique was applied to gas diffusion electrodes with low Pt-loadings of 0.102 and 0.029 mg/cm(2). Under oxygen atmosphere and 300 kPa(abs) total pressure, 88 kW/g(Pt) cathodic catalyst utilization efficiency with a symmetrical Pt-loading of 0.029 mg/cm(2) on the anode and cathode side was achieved. This is 23 times higher than the Pt-utilization efficiency of a reference fuel cell prepared using a commercial Nafion N-211 membrane and identical catalyst layers, emphasizing that the improvement is purely attributable to the novel membrane fabrication technique. This value represents the highest Pt-utilization efficiency reported in literature. The results strongly motivate the application of employing direct membrane deposition techniques to prepare low resistance polymer electrolyte thin films in order to compensate for kinetic losses introduced when using low catalyst loadings. (C) 2015 Elsevier B.V. All rights reserved.