Hydrothermal Syntheses, Crystal Structures, and Characterization of Two Zinc(II) Complexes Containing Flexible Bis(benzimidazole) Ligands

被引：2

作者：

Liu Xiao-Bing ^{[1
]}

Zhang Ze-Ting ^{[1
]}

Wang Yan-Yan ^{[1
]}

Liu Rui ^{[1
]}

Zhao Yong ^{[1
]}

Cui Guang-Hua ^{[1
]}

机构：

[1] North China Univ Sci & Technol, Coll Chem Engn, Tangshan 063009, Hebei, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2016年 / 35卷 / 11期

基金：

中国国家自然科学基金;

关键词：

bis(benzimidazole); catalytic property; crystal structure; fluorescence property; zinc(II) complex; COBALT(II) COORDINATION POLYMERS; N-DONOR LIGANDS; FRAMEWORK; ZN(II); ACID; PHOTOCATALYSTS; DEGRADATION; TOPOLOGIES; LINKERS;

D O I：

10.14102/j.cnki.0254-5861.2011-1160

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two zinc(II) complexes, namely, [Zn(L-1)Cl-2] 2 (1) and {[Zn(L-2)(tbta)]center dot 3H(2)O}(n) (2) (L-1 = 1,3-bis(2-methylbenzimidazol-1-ylmethyl) benzene, H(2)tbta = tetrabromoterephthalic acid, L-2 = 1,3-bis(2-methylbenzimidazol-1-yl)-2-propanol), have been successfully obtained under hydrothermal conditions. Complex 1 displays a binuclear structure which is further extended into a 1D supramolecular chain through pi-pi stacking. Complex 2 features a 2D (4,4) network based on a L-2/tbta(2-) double linker. The thermal stability, fluorescence properties and catalytic activities of two complexes for the degradation of methyl orange in a Fenton-like process were discussed.

引用

页码：1745 / 1753

页数：9

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