Hydrothermal Syntheses, Crystal Structures, and Luminescent Properties of Two Zinc(II) Coordination Polymers

被引：0

作者：

Liu, Haiyan ^{[1
]}

Jia, Anqiang ^{[2
]}

Wang, Zichen ^{[3
]}

Zhang, Lihui ^{[4
]}

机构：

[1] Agr Univ Hebei, Coll Sci, Baoding 071001, Peoples R China

[2] Agr Univ Hebei, Coll Rural & Urban Construct, Baoding 071001, Peoples R China

[3] Nankai Univ, Coll Chem, Tianjin 300071, Peoples R China

[4] Agr Univ Hebei, Coll Plant Protect, Baoding 071001, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2015年 / 641卷 / 10期

基金：

中国国家自然科学基金;

关键词：

Zinc; Hydrothermal synthesis; 3-Amino-1; 2; 4-triazole; Luminescence; ORGANIC FRAMEWORK; ZN(II); LIGAND;

D O I：

10.1002/zaac.201500227

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two zinc(II) compounds, namely [Zn-5(AmTAZ)(6)(OH)(2)](n)2n(NO3)6n(H2O) (1) and [Zn-3(AmTAZ)(2)(mal)(2)](n) (2) (HAmTAZ = 3-amino-1,2,4-triazole, H(2)mal = malonic acid), were hydrothermally synthesized and characterized by elemental analysis, IR spectroscopy, and X-ray diffraction. Single crystal X-ray diffraction analysis reveals that compound 1 features a 3D framework with dodecahedral cages occupied by free nitrate ions and lattice water molecules and can be reduced into a (4, 8)-connected flu topological network. Compound 2 features a 3D framework based on two different 1D chains. Moreover, the thermal stabilities and luminescent properties of compounds 1 and 2 were investigated.

引用

页码：1767 / 1771

页数：5

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