Syntheses and crystal structures of two novel zinc(II) coordination polymers

被引：71
|
作者：
Tao, J [1 ]
Yin, X
Jiang, YB
Yang, LF
Huang, RB
Zheng, LS
机构：
[1] Xiamen Univ, Dept Chem, Xiamen 361005, Peoples R China
[2] Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 14期
关键词：
coordination polymers; zinc; N ligands; hydrogen bonds; photoluminescence;
D O I：
10.1002/ejic.200300021
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two novel zinc(ii) coordination polymers, [Zn-3(mu(3)-OH)(2)(nip)(2)] (1) and [Zn-2(nip)(2)(4,4'-bpy)(3).(OH2)] (2) (H(2)nip = 5-nitroisophthalic acid, 4,4'-bpy = 4,4'-bipyridyl), were obtained by the hydrothermal reactions of zinc nitrate, 5-nitroisophthalate (nip) (for 1) and zinc nitrate, 5-nitroisophthalate and 4,4'-bipyridyl (for 2). Complex 1 displays a two-dimensional structure that is built from [Zn-3(mu(3)-OH)(2)](n) chains, while complex 2 is a three-dimensional structure formed by the interpenetration of two-dimensional hydrogen-bonded bilayers. The photoluminescent properties of complex 1 have also been investigated. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.
引用
收藏
页码：2678 / 2682
页数：5
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