Synthesis and characterization of ruthenium(II) hydrido and hydroxo complexes bearing the 2,6-bis(di-tert-butylphosphinomethyl)pyridine ligand

被引：28
|
作者：
Gibson, DH [1 ]
Pariya, C [1 ]
Mashuta, MS [1 ]
机构：
[1] Univ Louisville, Dept Chem, Louisville, KY 40292 USA
来源：
ORGANOMETALLICS | 2004年 / 23卷 / 10期
关键词：
D O I：
10.1021/om030659o
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of [Ru(CO)(2)Cl-2](n) with 2,6-bis-(di-tert-butylphosphinomethyl)pyridine) (PNP) and then anion exchange yields [Ru(PNP)(CO)(2)Cl]PF6 (1). Reaction of 1 with AgBF4, in acetone, followed by acetonitrile and then anion exchange gave [Ru(PNP)(CO)(2)(CH3CN)](PF6)(2) (2); reaction of 2 with water gave [Ru(PNP)(CO)(2)OH]PF6 (3), whereas reaction of 2 with aqueous KOH led to [Ru(PNP)(CO)(CH3CN)H]PF6 (4). Complexes 3 and 4 have been structurally characterized.
引用
收藏
页码：2510 / 2513
页数：4
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