Preparation and Reactivity of a Ruthenium Complex Bearing a 2,6-Bis(trimethylsilyl)benzenethiolate Ligand

被引：4

作者：

Yuki, Masahiro ^{[1
]}

Miyake, Yoshihiro ^{[1
]}

Nishibayashi, Yoshiaki ^{[1
]}

机构：

[1] Univ Tokyo, Inst Engn Innovat, Sch Engn, Bunkyo Ku, Tokyo 1138656, Japan

来源：

ORGANOMETALLICS | 2010年 / 29卷 / 18期

关键词：

BRIDGED DIRUTHENIUM COMPLEXES; PROPARGYLIC SUBSTITUTION-REACTIONS; IRON(II) THIOLATE COMPLEXES; RAY CRYSTAL-STRUCTURES; ASTERISK-RU COMPLEXES; AROMATIC-COMPOUNDS; CP-ASTERISK; MOLECULAR-STRUCTURE; CATALYZED PROPARGYLATION; ALCOHOLS;

D O I：

10.1021/om100689f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Cp*Ru(mu(3)-CI)](4) with ArSK (ArS = 2,6-(Me(3)Si)(2)C(6)H(3)S) gives the mononuclear ruthenium complex with pi-arenethiolate ligand [Cp*Ru(eta(5)-SAr)] via [Cp*Ru(mu-SArk](2.) Further reactions of [Cp*Ru(eta(5)-SAr)] with HCI and [Cp*Ru(mu(3)-CI)](4) give the corresponding monoruthenium complex [Cp*Ru(eta(6)-HSAr)]CI and diruthenium complex [Cp*Ru(mu-eta(5):eta(1)-SAr)RuCICp*] in high yields, respectively.

引用

页码：4148 / 4153

页数：6

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