Preparation and Reactivity of a Ruthenium Complex Bearing a 2,6-Bis(trimethylsilyl)benzenethiolate Ligand

被引：4
|
作者：
Yuki, Masahiro [1 ]
Miyake, Yoshihiro [1 ]
Nishibayashi, Yoshiaki [1 ]
机构：
[1] Univ Tokyo, Inst Engn Innovat, Sch Engn, Bunkyo Ku, Tokyo 1138656, Japan
来源：
ORGANOMETALLICS | 2010年 / 29卷 / 18期
关键词：
BRIDGED DIRUTHENIUM COMPLEXES; PROPARGYLIC SUBSTITUTION-REACTIONS; IRON(II) THIOLATE COMPLEXES; RAY CRYSTAL-STRUCTURES; ASTERISK-RU COMPLEXES; AROMATIC-COMPOUNDS; CP-ASTERISK; MOLECULAR-STRUCTURE; CATALYZED PROPARGYLATION; ALCOHOLS;
D O I：
10.1021/om100689f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of [Cp*Ru(mu(3)-CI)](4) with ArSK (ArS = 2,6-(Me(3)Si)(2)C(6)H(3)S) gives the mononuclear ruthenium complex with pi-arenethiolate ligand [Cp*Ru(eta(5)-SAr)] via [Cp*Ru(mu-SArk](2.) Further reactions of [Cp*Ru(eta(5)-SAr)] with HCI and [Cp*Ru(mu(3)-CI)](4) give the corresponding monoruthenium complex [Cp*Ru(eta(6)-HSAr)]CI and diruthenium complex [Cp*Ru(mu-eta(5):eta(1)-SAr)RuCICp*] in high yields, respectively.
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页码：4148 / 4153
页数：6
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