Vibrational spectroscopic investigations of 4-alkyl 4′-cyano biphenyls [CnH2n+1-C6H5-C6H5-CN, n=9, 10 and 11]

被引：3
|
作者：
Murty, KVGK [1 ]
Manisekharan, T [1 ]
Srinivasan, TKK [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Reg Sophisticated Instrumentat Ctr, Madras 600036, Tamil Nadu, India
来源：
MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2004年 / 408卷
关键词：
FT-IR; liquid crystals; Raman;
D O I：
10.1080/15421400490428259
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A complete vibrational analysis of liquid crystals 4-alkyl 4'-cyano biphenyls [CnH2n+1-C6H5-C6H5-CN, n=9, 10 and 11] is presented. The vibrational assignments are discussed in relation to their respective crystal structures. The vibrational bands in the CH stretching as well as CH2 wagging regions are effectively correlated to the crystal structures of the respective compounds. The ratios of IR and Raman intensities of the bands in the CH stretching region reveal the presence of disorder in the compounds.
引用
收藏
页码：83 / 102
页数：20
相关论文
共 50 条
  • [31] SPECTROSCOPIC INVESTIGATIONS OF THE IRON(II) NITROSODICYANOMETHANIDE AND NITROSOCARBAMOYLCYANOMETHANIDE COMPLEXES [FE(NOC(CN)2)2(C5H5N)4] AND [FE(NOC(CN)C(O)NH2)2(C5H5N)2]
    SKOPENKO, VV
    GERASIMCUK, NN
    TJUCHTENKO, SI
    KOHLER, H
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1986, 542 (11): : 65 - 70
  • [32] REACTIONS OF POLYOXOMOLYBDATES WITH OXIMES - THE CRYSTAL AND MOLECULAR-STRUCTURES OF [(C4H9)4N]2[MO2O5(C6H4(O)CHNO)2].CH2CL2 AND [(C4H9)4N]2[MO2O5(C6H5CH(O)C(NO)C6H5)2]
    LIU, SC
    ZHU, HZ
    ZUBIETA, J
    POLYHEDRON, 1989, 8 (20) : 2473 - 2480
  • [33] THE SYNTHESIS OF [(C4H9)4N]NK7-NNBW11O40H2 COMPLEX (N=5, 6)
    ZHAO, YC
    XIE, GY
    GU, YD
    ACTA CHIMICA SINICA, 1992, 50 (12) : 1178 - 1181
  • [34] Cation-pi interaction in Al(L)(+) complexes (L=C6H6, C5H5N, C5H6, C4H4NH, C4H4O)
    Stockigt, D
    JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (20): : 3800 - 3807
  • [35] Syntheses of (C5H9C5H4)2 LnCl(THF)n and Crystal Structures of [(C5H9C5H4)2SmCl(THF)]2 and [(C5H9C5H4)2ErCl]2
    金玑洙
    金钟声
    卫革成
    陈文启
    ChineseScienceBulletin, 1993, (06) : 526 - 527
  • [36] Ortho-mercurated [(N-methyl-N-arylaminolmethyl)ferrocenes] and their transpalladation.: Crystal structures of [(η5-C5H5)Fe{η5-C5H3 5H3(HgCl)CH2N(CH3)C6H4OCH3-4}]2 [(η5-C5H5)Fe{η5-C5H3(HgCl)CH2N(CH3)C6H4Cl-3] and [(η5 -C5H4HgCl)Fe{η5-C5H4CH2N(CH3)C6H4Cl-4]
    Wang, Hong-Xing
    Li, Ying-He
    Wu, Hong-Fei
    Gao, Ren-Qing
    Geng, Feng-Ying
    Yang, Xiao-Li
    Wan, Li
    Jin, Rong
    Cui, Xiu-Ling
    Wu, Yang-He
    POLYHEDRON, 2006, 25 (17) : 3305 - 3311
  • [37] Crystal structure of 2-amino-4-methylpyridininum 4-nitrobenzenesulfonate, [C6H9N2][C6H4NO5S]
    Hesami, Leila
    Tabatabaee, Masoumeh
    Ghassemzadeh, Mitra
    Rothenberger, Alexander
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2011, 226 (04): : 645 - 646
  • [38] Synthesis and crystal structure of [P(C6H5)(4)][2,9-{N,N'-(2-NH-(C5H4N))}B10H8]
    Nachtigal, C
    Preetz, W
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1997, 623 (09): : 1489 - 1491
  • [39] Vibrational spectroscopic investigations of M(imidazole)2 Ni(CN)4 • 2C6H12 clathrates
    Tufan, Y
    Karacan, N
    Davies, JED
    VIBRATIONAL SPECTROSCOPY, 2000, 23 (01) : 51 - 55
  • [40] STUDIESONSYNTHESIS,STRUCTUREANDPROPERTIESOFTHECRYSTALOFTRIADICCOMPLEX{Mo[S2CN（C2H5）2]4}+1{FeCl4}-1{C6H5CH2SSCH2C6H5}
    徐丽娟
    张致贵
    牛淑云
    李淑芹
    Science in China,SerB., 1982, Ser.B.1982 (08) : 815 - 821
12345