A Chemiluminescent Metal-Organic Framework

被引：32

作者：

Ruehle, Bastian ^{[1
,2
,3
]}

Virmani, Erika ^{[1
,2
]}

Engelke, Hanna ^{[1
,2
]}

Hinterholzinger, Florian M. ^{[1
,2
]}

von Zons, Tobias ^{[4
,5
]}

Brosent, Birte ^{[4
,5
]}

Bein, Thomas ^{[1
,2
]}

Godt, Adelheid ^{[4
,5
]}

Wuttke, Stefan ^{[1
,2
,6
]}

机构：

[1] Univ Munich LMU, Dept Chem, Butenandtstr 11 E, D-81377 Munich, Germany

[2] Univ Munich LMU, Ctr NanoSci CeNS, Butenandtstr 11 E, D-81377 Munich, Germany

[3] BAM Fed Inst Mat Res & Testing, Div Biophoton 1 2, Richard Willstaetter Str 11, D-12489 Berlin, Germany

[4] Bielefeld Univ, Fac Chem, Univ Str 25, D-33615 Bielefeld, Germany

[5] Bielefeld Univ, Ctr Mol Mat CM2, Univ Str 25, D-33615 Bielefeld, Germany

[6] Univ Lincoln, Sch Chem, Joseph Banks Labs, Lincoln LN6 7TS, England

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2019年 / 25卷 / 25期

关键词：

chemiluminescence; metal-organic framework; MOF; thin film; UiO; CATALYTIC CHEMILUMINESCENCE; PHOTOLUMINESCENCE; CHEMISTRY; SYSTEM;

D O I：

10.1002/chem.201806041

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and characterization of a chemiluminescent metal-organic framework with high porosity is reported. It consists of Zr6O6(OH)(4) nodes connected by 4,4'(anthracene-9,10-diyl) dibenzoate as the linker and luminophore. It shows the topology known for UiO-66 and is therefore denoted PAP-UiO. The MOF was not only obtained as bulk material but also as a thin film. Exposure of PAP-UiO as bulk or film to a mixture of bis-(2,4,6-trichlorophenyl) oxa-late, hydrogen peroxide, and sodium salicylate in a mixture of dimethyl and dibutyl phthalate evoked strong and long lasting chemiluminescence of the PAP-UiO crystals. Time dependent fluorescence spectroscopy on bulk PAP-UiO and, for comparison, on dimethyl 4,4'-(anthracene-9,10-diyl) dibenzoate provided evidence that the chemiluminescence originates from luminophores being part of the PAP-UiO, including the luminophores inside the crystals.

引用

页码：6349 / 6354

页数：6

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