Triselenium dicyanide from malononitrile and selenium dioxide. One-pot synthesis of selenocyanates

被引：77
|
作者：
Kachanov, AV [1 ]
Slabko, OY [1 ]
Baranova, OV [1 ]
Shilova, EV [1 ]
Kaminskii, VA [1 ]
机构：
[1] Far Eastern Natl Univ, Dept Chem, Vladivostok 690000, Russia
来源：
TETRAHEDRON LETTERS | 2004年 / 45卷 / 23期
关键词：
triselenium dicyanide; selenocyanate; malononitrile;
D O I：
10.1016/j.tetlet.2004.04.071
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Triselenium dicyanide is formed by the interaction of malononitrile and selenium dioxide in dimethylsulfoxide or dimethylformamide. Addition of aromatic amines, indoles and some active methylene compounds to this reaction mixture gives the corresponding selenocyanates in one-pot. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4461 / 4463
页数：3
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