Structural analysis and magnetic properties of the 2-D compounds [M(N3)2(bpa)]n (M = Mn, Co or Ni; bpa = 1,2-bis(4-pyridyl)ethane)

被引：72

作者：

Hernández, ML

Barandika, MG

Urtiaga, MK

Cortés, R

Lezama, L

Arriortua, MI

机构：

[1] Univ Basque Country, Fac Ciencias, Dept Mineral Petrol, E-48080 Bilbao, Spain

[2] Univ Basque Country, Fac Ciencias, Dept Quim Inorgan, E-48080 Bilbao, Spain

[3] Univ Basque Country, Fac Farm, Dept Quim Inorgan, Vitoria 01080, Spain

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 01期

关键词：

D O I：

10.1039/a906154a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Isomorphous compounds exhibiting the general formula [M(N-3)(2)(bpa)](n) (M=Mn-II 1, Co-II 2 or Ni-II 3; bpa=1,2-bis(4-pyridyl)ethane) have been prepared and magnetostructurally characterised. X-Ray diffraction analysis revealed a 2-D arrangement of octahedrally co-ordinated metal cations where di-mu-(1,3)-N-3-bridged metallic chains are connected through bpa ligands. IR and UV-VIS spectra were consistent with this structural characterisation. Magnetic analysis carried out by means of ESR spectroscopy and susceptibility measurements indicated that the three compounds are antiferromagnetic, J values being -5.7, -14.0 and -80 cm(-1) for 1, 2 and 3, respectively.

引用

页码：79 / 84

页数：6

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