Structural analysis and magnetic properties of the 2-D compounds [M(N3)2(bpa)]n (M = Mn, Co or Ni; bpa = 1,2-bis(4-pyridyl)ethane)

被引：72
|
作者：
Hernández, ML
Barandika, MG
Urtiaga, MK
Cortés, R
Lezama, L
Arriortua, MI
机构：
[1] Univ Basque Country, Fac Ciencias, Dept Mineral Petrol, E-48080 Bilbao, Spain
[2] Univ Basque Country, Fac Ciencias, Dept Quim Inorgan, E-48080 Bilbao, Spain
[3] Univ Basque Country, Fac Farm, Dept Quim Inorgan, Vitoria 01080, Spain
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 01期
关键词：
D O I：
10.1039/a906154a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Isomorphous compounds exhibiting the general formula [M(N-3)(2)(bpa)](n) (M=Mn-II 1, Co-II 2 or Ni-II 3; bpa=1,2-bis(4-pyridyl)ethane) have been prepared and magnetostructurally characterised. X-Ray diffraction analysis revealed a 2-D arrangement of octahedrally co-ordinated metal cations where di-mu-(1,3)-N-3-bridged metallic chains are connected through bpa ligands. IR and UV-VIS spectra were consistent with this structural characterisation. Magnetic analysis carried out by means of ESR spectroscopy and susceptibility measurements indicated that the three compounds are antiferromagnetic, J values being -5.7, -14.0 and -80 cm(-1) for 1, 2 and 3, respectively.
引用
收藏
页码：79 / 84
页数：6
相关论文
共 50 条
  • [11] Weak Ferromagnetism Caused by a 2D Effect in Two New Cobalt(II)- and Nickel(II)-1,2-Bis(4-pyridyl)ethane (bpa) Polynuclear Compounds
    de la Pinta, Noelia
    Madariaga, Gotzon
    Lezama, Luis
    Luz Fidalgo, M.
    Cortes, Roberto
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2010, (22) : 3491 - 3497
  • [12] Crystal structure of catena-poly[triaqua(μ2-1,2-bis(4-pyridyl)ethane-κ2N:N′)-(1,2-bis(4-pyridyl)ethane-κN)nickel(II)] 2-aminonicotinate nitrate-1,2-bis(4-pyridyl)ethane - water (2/1/8), C36H44N8NiO12
    Wang, Yu-Fang
    Wei, Jing-jing
    Zhai, Xiao-Hui
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2018, 233 (03): : 383 - 385
  • [13] Flexible bilayer architectures in the coordination polymers [MII(NO3)2(1,2-bis(4-pyridyl)ethane)1.5]n (MII = Co, Ni)
    Atencio, R
    Biradha, K
    Hennigar, TL
    Poirier, KM
    Power, KN
    Seward, CM
    White, NS
    Zaworotko, MJ
    MATERIALS RESEARCH BULLETIN, 1998, : 203 - 212
  • [14] Novel lanthanide(III) coordination networks based on 1,2-bis(4-pyridyl)-ethane-N,N′-dioxide and trans-1,2 bis(4-pyridyl)ethene-N,N′-dioxide
    Lu, WJ
    Zhang, LP
    Song, HB
    Wang, QM
    Mak, TCW
    NEW JOURNAL OF CHEMISTRY, 2002, 26 (06) : 775 - 781
  • [15] Perpendicular interpenetration of independent square grid sheets.: Synthesis and structural properties of [Co(NCS)2(Py2L)2]n (Py2L=trans-1,2-bis(4-pyridyl)ethylene, 1,2-bis(4-pyridyl)ethane)
    Park, SH
    Kim, KM
    Lee, S
    Jung, OS
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1998, 19 (01) : 79 - 82
  • [16] Occurrence of the spin-crossover phenomenon of assembled complexes, Fe(NCX)2(bpa)2 (X = S, BH3;: bpa=1,2-bis(4-pyridyl)ethane) by enclathrating organic guest molecule
    Morita, Takaki
    Nakashima, Satoru
    Yamada, Koji
    Inoue, Katsuya
    CHEMISTRY LETTERS, 2006, 35 (09) : 1042 - 1043
  • [17] catena-poly[[silver(I)-μ-1,2-bis(4-pyridyl)-ethane-κ2N:N′] trifluoromethanesulfonate]
    Li, XJ
    Cao, R
    Sun, DF
    Bi, WH
    Wang, YQ
    Hong, MC
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2003, 59 : M416 - M418
  • [18] Supramolecular isomerism in coordination polymers: Conformational freedom of ligands in [Co(NO3)(2)(1,2-bis(4-pyridyl)ethane)(1.5)](n)
    Hennigar, TL
    MacQuarrie, DC
    Losier, P
    Rogers, RD
    Zaworotko, MJ
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (09) : 972 - 973
  • [19] Supramolecular Isomerism in Coordination Polymers: Conformational Freedom of Ligands in [Co(NO3)2(1,2-bis(4-pyridyl)ethane)1.5] n
    Hennigar, Tracy L.
    MacQuarrie, Donald C.
    Losier, Pierre
    Rogers, Robin D.
    Zaworotko, Michael J.
    Angewandte Chemie (International Edition in English), 1997, 36 (09): : 972 - 973
  • [20] Synthesis and Characterization of New 2D Coordination Polymers based on Mn(NCS)2 and Ni(NCS)2 with 1,2-Bis(4-pyridyl)-ethane as Co-Ligand
    Woehlert, Susanne
    Fink, Lothar
    Schmidt, Martin U.
    Naether, Christian
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2013, 639 (12-13): : 2186 - 2194
12345