Ultra-low-energy ion-beam-synthesis of Ge nanocrystals in thin ALD Al2O3 layers for memory applications

被引:9
|
作者
Dimitrakis, P. [1 ]
Mouti, A. [2 ]
Bonafos, C. [2 ]
Schamm, S. [2 ]
Ben Assayag, G. [2 ]
Ioannou-Sougleridis, V. [1 ]
Schmidt, B. [3 ]
Becker, J. [4 ]
Normand, P. [1 ]
机构
[1] NCSR Demokritos, Inst Microelect, Aghia Paraskevi 15310, Greece
[2] Univ Toulouse, CNRS, CEMES, Toulouse, France
[3] Res Ctr Dresden Rossendorf, Dresden, Germany
[4] Cambridge NanoTech Inc, Cambridge, MA USA
关键词
Ion implantation; Ge nanocrystals; Nanocrystal memory; MOS CAPACITORS;
D O I
10.1016/j.mee.2009.03.074
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Structural and electrical properties of ALD-grown 5 and 7 nm-thick Al2O3 layers before and after implantation of Ge ions (1 keV, 0.5(-1) x 10(16) cm(-2)) and thermal annealing at temperatures in the 700-1050 degrees C range are reported. Transmission Electron Microscopy reveals the development of a 1 rim-thick SiO2-rich layer at the Al2O3/Si substrate interface as well as the formation of Ge nanocrystals with a mean diameter of similar to 5 nm inside the implanted Al2O3 layers after annealing at 800 degrees C for 20 min. Electrical measurements performed on metal-insulator-semiconductor capacitors using Ge-implanted and annealed Al2O3 layers reveal charge storage at low-electric fields mainly due to location of the Ge nanocrystals at a tunnelling distance from the substrate and their spatial dispersion inside the Al2O3 layers. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:1838 / 1841
页数:4
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