Synthesis and crystal structure of a new phenoxy oxygen bridged binuclear cadmium(II) polyaza cryptate

被引：19
|
作者：
Xu, XY
Chen, JL
Luo, QH
Shen, MC
Huang, XY
Wu, QJ
机构：
[1] NANJING UNIV,INST COORDINAT CHEM,STATE KEY LAB COORDINAT CHEM,NANJING 210093,PEOPLES R CHINA
[2] FUZHOU STATE KEY LAB STRUCT CHEM,FUZHOU 350002,PEOPLES R CHINA
来源：
POLYHEDRON | 1997年 / 16卷 / 02期
关键词：
cadmium(II); cryptate; crystal structure; polyaza; binuclear; phenoxy oxygen bridge;
D O I：
10.1016/0277-5387(96)00279-3
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new tris(phenoxy oxygen) bridged bicadmium(II) polyaza cryptate has been synthesized by [2+3] Schiff-base condensation of tris(3-aminopropyl)amine with sodium 2,6-diformyl-4-methylphenolate in the presence of Cd(ClO4)(2) . 6H(2)O. The crystal structure, characterization of spectra and molar conductivity shows that two cadmium(II) atoms were bridged by three phenoxy oxygen atoms. Each cadmium(II) located in a seven coordination environment (N4O3). The coordination geometry around the Cd-II is a capped distorted octahedron. Copyright (C) 1996 Elsevier Science Ltd.
引用
收藏
页码：223 / 227
页数：5
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