Synthesis and crystal structure of a chlorido-bridged dinuclear cadmium(II) complex with a tetraaza macrocycle

被引：0
|
作者：
Lim, In-Taek [1 ]
Choi, Ki-Young [1 ]
机构：
[1] Kongju Natl Univ, Dept Chem Educ, Kong Ju 314701, South Korea
来源：
MAIN GROUP METAL CHEMISTRY | 2011年 / 34卷 / 1-2期
关键词：
chlorido-bridged dinuclear complex; crystal structure; dinuclear cadmium(II) complex; distorted square-pyramid; tetraaza macrocycle; LIGANDS;
D O I：
10.1515/MGMC.2011.006
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The dinuclear cadmium(II) complex [Cd-II(L)(mu-Cl)(CdCl3)-Cl-II] (1) (L=3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,0(1.18),0(7.12)] docosane) has been synthesized and structurally characterized by X-ray diffraction. The compound 1 crystallizes in the monoclinic system P2(1)/n with a=8.45380(10), b=18.2348(3), c=17.4271(3) angstrom, beta=100.957(1)degrees, V=2637.47(7) angstrom(3), Z=4. The crystal structure of 1 reveals a chlorido-bridged dinuclear complex, in which the coordination environment around each cadmium atom exhibits a distorted square-pyramid and a distorted tetrahedron, respectively. Cyclic voltammetry of 1 gives one oxidation and two reduction processes.
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页码：43 / 46
页数：4
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