Copper-Catalyzed Synthesis of Mixed Alkyl Aryl Phosphonates

被引：60

作者：

Fananas-Mastral, Martin ^{[1
]}

Feringa, Ben L. ^{[1
]}

机构：

[1] Univ Groningen, Stratingh Inst Chem, NL-9747 AG Groningen, Netherlands

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 28期

基金：

欧洲研究理事会;

关键词：

H BOND ARYLATION; DIARYLIODONIUM SALTS; POLYVALENT IODINE; MEDICINAL CHEMISTRY; ROOM-TEMPERATURE; NERVE AGENTS; ESTERS; ACID; PALLADIUM; INDOLES;

D O I：

10.1021/ja505281v

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Copper-catalysis allows the direct oxygenarylation of dialkyl phosphonates with diaryliodonium salts. This novel methodology proceeds with a wide range of phosphonates and phosphoramidates under mild conditions and gives straightforward access to valuable mixed alkyl aryl phosphonates in very good yields and near perfect selectivity.

引用

页码：9894 / 9897

页数：4

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