Synthesis of triarylamines by copper-catalyzed amination of aryl halides

被引：29
|
作者：
Patil, NM [1 ]
Kelkar, AA [1 ]
Chaudhari, RV [1 ]
机构：
[1] Natl Chem Lab, Homogeneous Catalysis Div, Pune 411008, Maharashtra, India
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2004年 / 223卷 / 1-2期
关键词：
amination; copper catalyst; triphenylamine; arylamines;
D O I：
10.1016/j.molcata.2003.09.038
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A simple and efficient methodology for the synthesis of triphenylamine (TPA) in a single step has been demonstrated using copper catalyst with a ligand. The effect of parameters such as catalyst precursors, ligands, bases and solvents on activity and selectivity to triphenylamine were studied at 115degreesC. Best results were obtained using 2,6-diphenylpyridine as a ligand (94% yield of TPA). (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：45 / 50
页数：6
相关论文
共 50 条
  • [1] Copper-catalyzed amination of aryl halides: single-step synthesis of triarylamines
    Kelkar, AA
    Patil, NM
    Chaudhari, RV
    [J]. TETRAHEDRON LETTERS, 2002, 43 (40) : 7143 - 7146
  • [2] Copper-Catalyzed Synthesis of Triarylamines from Aryl Halides and Arylamines
    Qian Cunwei
    Xu Shaojie
    Zong Qianshou
    Fang Dong
    [J]. CHINESE JOURNAL OF CHEMISTRY, 2012, 30 (08) : 1881 - 1885
  • [3] Synthesis of N-Arylamides by Copper-Catalyzed Amination of Aryl Halides with Nitriles
    Xiang, Shi-Kai
    Zhang, Dong-Xue
    Hu, Hao
    Shi, Jiang-Ling
    Liao, Li-Guo
    Feng, Chun
    Wang, Bi-Qin
    Zhao, Ke-Qing
    Hu, Ping
    Yang, Hua
    Yu, Wen-Hao
    [J]. ADVANCED SYNTHESIS & CATALYSIS, 2013, 355 (08) : 1495 - 1499
  • [4] An Efficient Copper-Catalyzed Amination of Aryl Halides by Aqueous Ammonia
    Wang, Deping
    Cai, Qian
    Ding, Ke
    [J]. ADVANCED SYNTHESIS & CATALYSIS, 2009, 351 (11-12) : 1722 - 1726
  • [5] Selective Copper-Catalyzed Azidation and Amination of Aryl Halides with Sodium Azide
    Paik, Seunguk
    [J]. APPLIED CHEMISTRY FOR ENGINEERING, 2021, 32 (02): : 224 - 227
  • [6] A new ligand for copper-catalyzed amination of aryl halides to primary (hetero)aryl amines
    Jiang, Shang
    Dong, Xinrui
    Qiu, Yatao
    Chen, Dong
    Wu, Xiaoxing
    Jiang, Sheng
    [J]. TETRAHEDRON LETTERS, 2020, 61 (13)
  • [7] A simple and efficient copper-catalyzed amination of aryl halides by aqueous ammonia in water
    Zhu, Yefeng
    Wei, Yunyang
    [J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 2011, 89 (06): : 645 - 649
  • [8] Copper-Catalyzed Amination of Aryl Halides with Aqueous Ammonia under Mild Conditions
    Quan, Zhengjun
    Xia, Haidong
    Zhang, Zhang
    Da, Yuxia
    Wang, Xicun
    [J]. CHINESE JOURNAL OF CHEMISTRY, 2013, 31 (04) : 501 - 506
  • [9] Copper-Catalyzed Amination of Alkenyl Halides: Efficient Method for the Synthesis of Enamines
    Wang, Yuxing
    Liao, Qian
    Xi, Chanjuan
    [J]. ORGANIC LETTERS, 2010, 12 (13) : 2951 - 2953
  • [10] Efficient Copper-Catalyzed Direct Amination of Aryl Halides Using Aqueous Ammonia in Water
    Meng, Fei
    Zhu, Xinhai
    Li, Ying
    Xie, Jianwei
    Wang, Bo
    Yao, Junhua
    Wan, Yiqian
    [J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2010, 2010 (32) : 6149 - 6152
12345