Copper-Catalyzed Synthesis of Triarylamines from Aryl Halides and Arylamines

被引：11

作者：

Qian Cunwei ^{[1
]}

Xu Shaojie ^{[1
]}

Zong Qianshou ^{[2
]}

Fang Dong ^{[1
]}

机构：

[1] Yancheng Teachers Univ, Sch Chem & Chem Engn, Yancheng 224051, Jiangsu, Peoples R China

[2] Jiaxing Univ, Sch Biol & Chem Engn, Jiaxing 314001, Zhejiang, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2012年 / 30卷 / 08期

关键词：

copper catalyst; Ullmann coupling; triphenylamine; synthesis; ROOM-TEMPERATURE AMINATION; N BOND FORMATION; C-N; COUPLING REACTIONS; ULLMANN SYNTHESIS; HIGHLY EFFICIENT; ARYLATION; AMINES; LIGAND; BROMIDES;

D O I：

10.1002/cjoc.201200247

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple and efficient methodology for the synthesis of triphenylamines has been demonstrated using copper catalyst with a ligand and tripotassium phosphate as the base. The effect of parameters such as catalyst precursors, ligands, bases and solvents were studied and a series of triphenylamines were obtained with moderate to excellent yields in DMF. This reaction displays great functional groups compatibility in the presence of a broad range of functional groups.

引用

页码：1881 / 1885

页数：5

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