Palladium/copper-catalyzed arylation of alkenes with N′-acyl arylhydrazines

被引:15
|
作者
Zhang, Ji-Quan [1 ]
Cao, Jun [1 ]
Li, Wei [1 ]
Li, Shu-Min [1 ]
Li, Yong-Kang [2 ]
Wang, Jian-Ta [1 ]
Tang, Lei [1 ]
机构
[1] Guizhou Med Univ, Coll Pharm, Guiyang 550004, Peoples R China
[2] Guiyang 1 Middle Sch, Guiyang 550081, Peoples R China
关键词
C-BOND FORMATION; COUPLING REACTIONS; DIAZONIUM SALTS; HECK REACTION; CLEAVAGE; ARYL; OLEFINATION; ACTIVATION; INHIBITORS; ACIDS;
D O I
10.1039/c6nj03718f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel ligand-free palladium/copper-catalyzed Heck-type coupling reaction of alkenes and N' -acyl arylhydrazines has been developed by using air as the terminal oxidant. This protocol features wide functional group tolerance and produces highly chemoselective and regioselective products with good to excellent yields.
引用
收藏
页码:437 / 441
页数:5
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