Quantitative aspects of the effects of halide and azide ions on the acid-catalyzed hydrolysis of (±)-7β-8α-dihydroxy-9α,10α-epoxy-7,8,9,10-tetrahydrobenzo[a]pyrene

被引：1

作者：

Lin, B ^{[1
]}

Doan, L

Yagi, H

Jerina, DM

Whalen, D

机构：

[1] Univ Maryland Baltimore Cty, Dept Chem & Biochem, Baltimore, MD 21228 USA

[2] NCI, Bioorgan Chem Lab, Bethesda, MD 20892 USA

来源：

POLYCYCLIC AROMATIC COMPOUNDS | 1999年 / 16卷 / 1-4期

关键词：

benzo[a]pyrene diol epoxides; hydrolysis; halohydrins;

D O I：

10.1080/10406639908020575

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Mechanisms of the acid-catalyzed reactions of (+/-)-7 beta, 8 alpha-dihydroxy-9 alpha, 10 alpha-epoxy-7, 8, 9, 10-tetrahydrobenzo[a]pyrene (1) in 1:9 dioxane-water solutions containing varying concentrations of KCl, KBr, NaI, NaN3 and NaClO4 are discussed.

引用

页码：79 / 88

页数：10

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