Quantitative aspects of the effects of halide and azide ions on the acid-catalyzed hydrolysis of (±)-7β-8α-dihydroxy-9α,10α-epoxy-7,8,9,10-tetrahydrobenzo[a]pyrene

被引：1
|
作者：
Lin, B [1 ]
Doan, L
Yagi, H
Jerina, DM
Whalen, D
机构：
[1] Univ Maryland Baltimore Cty, Dept Chem & Biochem, Baltimore, MD 21228 USA
[2] NCI, Bioorgan Chem Lab, Bethesda, MD 20892 USA
来源：
POLYCYCLIC AROMATIC COMPOUNDS | 1999年 / 16卷 / 1-4期
关键词：
benzo[a]pyrene diol epoxides; hydrolysis; halohydrins;
D O I：
10.1080/10406639908020575
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Mechanisms of the acid-catalyzed reactions of (+/-)-7 beta, 8 alpha-dihydroxy-9 alpha, 10 alpha-epoxy-7, 8, 9, 10-tetrahydrobenzo[a]pyrene (1) in 1:9 dioxane-water solutions containing varying concentrations of KCl, KBr, NaI, NaN3 and NaClO4 are discussed.
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页码：79 / 88
页数：10
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