catena-Poly[hemi{bis[4′-(3-pyridyl)-2,2′:6′,2"-terpyridine-κ3N1,N1′,N1"]copper(II)} [cuprate(I)-di-μ2-thiocyanato-κ2N:S;κ2S:N]]

被引：2
|
作者：
Shi, Wen-Juan
机构：
[1] Jiangxi Key Laboratory of Surface Engineering, Jiangxi Science and Technology Normal University
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词：
METAL-COMPLEXES;
D O I：
10.1107/S1600536809023356
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, {[Cu(C20H14N4)(2)][Cu-2(NCS)(4)]}(n), was obtained by reacting copper acetate hydrate, ammonium thiocyanate and 4'-(3-pyridyl)-2,2':6',2 ''-terpyridine (3-pytpy) under solvothermal conditions. The polymeric complex is isostructural with the 4'-phenyl-2,2': 6',2 ''-terpyridine (phtpy) analogue. All intramolecular distances and angles are very similar for the two structures. Substitution of a phenyl group with a pyridyl group has no significant effect on the crystal packing which is accomplished by C-H center dot center dot center dot N and C-H center dot center dot center dot S hydrogen-bonding interactions.
引用
收藏
页码：M814 / U1192
页数：16
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