catena-Poly[[(1,10-phenanthroline-κ2N,N′)copper(I)]-μ-thiocyanato-κ2N:S-[(1,10-phenanthroline-κ2N,N′)copper(I)]-μ-cyanido-κ2N:C]

被引：0

作者：

Zhao, Jun ^{[1
]}

Dong, Wen-Wen ^{[1
]}

Li, Dong-Sheng ^{[1
]}

Ke, Xi-Jun ^{[1
]}

机构：

[1] Three Gorges Univ, Funct Mat Res Inst, Coll Mech & Mat Engn, Yichang 443002, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1107/S1600536808037744

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title complex, [Cu-2(CN)(NCS)(C12H8N2)(2)], which was synthesized under hydrothermal conditions, both Cu-I atoms have a slightly distorted tetrahedral geometry. They are coordinated by two N atoms of one 1,10-phenanthroline ligand, one bridging thiocyanate anion and one bridging cyanide anion. In the crystal structure, infinite helical {Cu-CN-Cu-SCN}(n) chains are formed along [(1) over bar 01].

引用

页码：M1577 / U905

页数：12

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