Rapid recrystallisation and surface modification of titanium by electro discharge

2.0 to 3.5 kJ of input energy as a single pulse from a 150 mu F capacitor was applied to a 50% cold rolled Ti to induce rapid recrystallisation and surface modification. Using an input energy of 2.0 kJ, complete recrystallisation occurred over a period of 96 mu s and the resulting microstructure was identical to that of a Ti before cold rolling. With an input energy of 2.5 kJ or higher, thermal oxycarburisation progressed by the formation of a titanium oxycarbide layer and the activation energy for the associated diffusion process was calculated to be 231 kJ mol(-1). A much higher value of hardness that was observed at the edge of the cross section was attributed to oxygen and carbon induced solid solution hardening. Both the recrystallisation and surface modification processes depended on the amount of heat generated during an electro discharge, which could be manipulated by input energy and capacitance.