Free radical formation during ethylbenzene oxidation catalyzed by cetyltrimethylammonium bromide

被引：19
|
作者：
Pisarenko, LM [1 ]
Kasaikina, OT [1 ]
机构：
[1] Russian Acad Sci, NN Semenov Chem Phys Inst, Moscow 119991, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2002年 / 51卷 / 03期
关键词：
2,2 '-bis[2-(p-dimetliylaminophenyl)indane-1,3-dione; cetyltrimethylammonium bromide; ethylbenzene oxidation; catalysis; free radicals;
D O I：
10.1023/A:1015552100977
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The dimer of 2,2'-bis[2-(p-dimethylaminophenyl)indane-1,3-dione] and alpha-tocopherol were used as free radical acceptors in a study of the kinetic regularities of free radical formation during ethylbenzene oxidation by molecular oxygen at 60 degreesC. The reaction initiated by the alpha-phenylethyl hydroperoxide-cetyltrimethylammonium bromide (CTAB) catalytic system, which generates free radicals. The oxidation kinetics was analyzed using computer simulation.
引用
收藏
页码：449 / 456
页数：8
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